High Precision Determination of Mercury Isotope Ratios Using Online Mercury Vapor Generation System Coupled with Multi-collector Inductively Coupled Plasma-Mass Spectrometry
文献类型:期刊论文
作者 | Delphine Foucher; Wen-Fang SHI; Zhi-Qi ZHAO; Jing WANG; Xin-Bin FENG; Run-Sheng YIN |
刊名 | Chinese Journal of Analytical Chemistry
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出版日期 | 2010 |
卷号 | 38期号:7页码:929-934 |
英文摘要 | In this study, a method for high-precision measurement of Hg isotope ratios by multiple collector inductively coupled plasma-mass spectrometry (MC-ICP-MS) with on-line Hg reduction technique was developed. The procedure was evaluated to obtain high-precision measurements that were good enough to significantly detect the anticipated small differences in Hg isotope compositions in natural samples. Typically, internal precision was better than 0.02%° (1 RSE) on all Hg ratios investigated. The external reproducibility for standard NIST SRM3133 and UM-Almadén secondary solution, nature samples were 0.06%° (2SD) and 0.10%° (2SD) over a period of 7 months, respectively. The extent of fractionation has been investigated in a series of natural samples from different locations in China. The ratio 202Hg/198Hg expressed as δ values (per mil deviations relative to NIST SRM 3133 Hg standard solution) displayed differences from –3.48%° to 0.633%°. These results indicated a wide perspective application of tracing Hg in the environment. |
学科主题 | 环境地球化学 |
语种 | 英语 |
公开日期 | 2017-12-19 |
源URL | [http://ir.gyig.ac.cn:8080/handle/352002/6805] ![]() |
专题 | 地球化学研究所_环境地球化学国家重点实验室_环境地球化学国家重点实验室_期刊论文 地球化学研究所_环境地球化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Delphine Foucher,Wen-Fang SHI,Zhi-Qi ZHAO,et al. High Precision Determination of Mercury Isotope Ratios Using Online Mercury Vapor Generation System Coupled with Multi-collector Inductively Coupled Plasma-Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry,2010,38(7):929-934. |
APA | Delphine Foucher,Wen-Fang SHI,Zhi-Qi ZHAO,Jing WANG,Xin-Bin FENG,&Run-Sheng YIN.(2010).High Precision Determination of Mercury Isotope Ratios Using Online Mercury Vapor Generation System Coupled with Multi-collector Inductively Coupled Plasma-Mass Spectrometry.Chinese Journal of Analytical Chemistry,38(7),929-934. |
MLA | Delphine Foucher,et al."High Precision Determination of Mercury Isotope Ratios Using Online Mercury Vapor Generation System Coupled with Multi-collector Inductively Coupled Plasma-Mass Spectrometry".Chinese Journal of Analytical Chemistry 38.7(2010):929-934. |
入库方式: OAI收割
来源:地球化学研究所
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