中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
High performance cocktail functional monomer for making molecule imprinting polymer

文献类型:期刊论文

作者Meng, ZH; Wang, JF; Zhou, LM; Wang, QH; Zhu, DQ
刊名analytical sciences
出版日期1999-02-01
卷号15期号:2页码:141-144
关键词molecule imprinting enantiomer separation chiral stationary phase amino acid
英文摘要in order to make a molecule imprinting polymer (mip) with highly chiral selectivity against n-t-boc-l-trp, a new kind of "cocktail" functional monomer: acrylamide+2-vinylpyridine was investigated. the mip showed impressive chiral selectivity (alpha=3.23). with the increasing of water content in the mobile phase, ionic and hydrophobic interaction were found to be responsible for the chiral recognition process instead of the hydrogen bond. tailing and peak asymmetry problems were overcome by using linear gradient elution. physical properties such as thermal stability and pore structure for the mip were also investigated.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, analytical
研究领域[WOS]chemistry
关键词[WOS]chiral stationary-phase ; resolution
收录类别SCI
原文出处true
语种英语
WOS记录号WOS:000078551300006
公开日期2010-11-30
源URL[http://159.226.238.44/handle/321008/86809]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem & Phys, Dalian 116012, Peoples R China
推荐引用方式
GB/T 7714
Meng, ZH,Wang, JF,Zhou, LM,et al. High performance cocktail functional monomer for making molecule imprinting polymer[J]. analytical sciences,1999,15(2):141-144.
APA Meng, ZH,Wang, JF,Zhou, LM,Wang, QH,&Zhu, DQ.(1999).High performance cocktail functional monomer for making molecule imprinting polymer.analytical sciences,15(2),141-144.
MLA Meng, ZH,et al."High performance cocktail functional monomer for making molecule imprinting polymer".analytical sciences 15.2(1999):141-144.

入库方式: OAI收割

来源:大连化学物理研究所

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