中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
SrB4O7:Sm2+: an optical sensor reflecting non-hydrostatic pressure at high-temperature and/or high pressure in a diamond anvil cell

文献类型:期刊论文

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作者Chaoshuai Zhao; Heping Li; Yan Wang; Jianjun Jiang; Yu He
刊名High Pressure Research ; High Pressure Research
出版日期2017 ; 2017
页码18-27
关键词Srb4o7:Sm2++ Srb4o7:Sm2++ High Pressure High-temperature Non-hydrostatic Pressure Fwhm High Pressure High-temperature Non-hydrostatic Pressure Fwhm
英文摘要

A systematic investigation on the fluorescent spectra of SrB4O7:Sm2+ was performed in detail at high-temperature up to 623 K and/or high pressure up to 23.2 GPa with different pressure-transmitting media (PTMs), respectively. Combined with experiment data of previous research, the change of the 7 D0–5 F0 line (0–0 line) full width at half maximum (FWHM) of SrB4O7:Sm2+ under different pressure environments was specifically discussed. The results indicate that the FWHM of 0–0 line is sensitive to the nonhydrostatic pressure environment in 2-propanol, and methanol and ethanol mixture (ME) PTMs at ambient temperature. The firstorder and the second-order derivation of the temperature dependence of 0–0 line FWHM at ambient pressure are 1.48 (±0.21) × 10−4 nm/K and 9.63(±0.63) × 10−7 nm2 /K2 below 623 K. The 0–0 line FWHM is also sensitive to the non-hydrostatic pressure environment in ME at high-temperature and high pressure simultaneous, the non-hydrostatic transition pressures are 9.6 GPa at 323 K, 11.0 GPa at 373 K, 14.4 GPa at 423 K, respectively. SrB4O7:Sm2+ is recommended as an optical sensor to reflect the change of pressure environment in liquid media at high-temperature and/or high pressure.

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A systematic investigation on the fluorescent spectra of SrB4O7:Sm2+ was performed in detail at high-temperature up to 623 K and/or high pressure up to 23.2 GPa with different pressure-transmitting media (PTMs), respectively. Combined with experiment data of previous research, the change of the 7 D0–5 F0 line (0–0 line) full width at half maximum (FWHM) of SrB4O7:Sm2+ under different pressure environments was specifically discussed. The results indicate that the FWHM of 0–0 line is sensitive to the nonhydrostatic pressure environment in 2-propanol, and methanol and ethanol mixture (ME) PTMs at ambient temperature. The firstorder and the second-order derivation of the temperature dependence of 0–0 line FWHM at ambient pressure are 1.48 (±0.21) × 10−4 nm/K and 9.63(±0.63) × 10−7 nm2 /K2 below 623 K. The 0–0 line FWHM is also sensitive to the non-hydrostatic pressure environment in ME at high-temperature and high pressure simultaneous, the non-hydrostatic transition pressures are 9.6 GPa at 323 K, 11.0 GPa at 373 K, 14.4 GPa at 423 K, respectively. SrB4O7:Sm2+ is recommended as an optical sensor to reflect the change of pressure environment in liquid media at high-temperature and/or high pressure.

语种英语 ; 英语
源URL[http://ir.gyig.ac.cn/handle/42920512-1/8421]  
专题地球化学研究所_地球内部物质高温高压实验室
地球深部物质与流体作用地球化学研究室
作者单位1.Key Laboratory for High-temperature and High-pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, People’s Republic of China
2.College of Earth Sciences,University of Chinese Academy of Sciences, Beijing, People’s Republic of China
推荐引用方式
GB/T 7714
Chaoshuai Zhao,Heping Li,Yan Wang,et al. SrB4O7:Sm2+: an optical sensor reflecting non-hydrostatic pressure at high-temperature and/or high pressure in a diamond anvil cell, SrB4O7:Sm2+: an optical sensor reflecting non-hydrostatic pressure at high-temperature and/or high pressure in a diamond anvil cell[J]. High Pressure Research, High Pressure Research,2017, 2017:18-27, 18-27.
APA Chaoshuai Zhao,Heping Li,Yan Wang,Jianjun Jiang,&Yu He.(2017).SrB4O7:Sm2+: an optical sensor reflecting non-hydrostatic pressure at high-temperature and/or high pressure in a diamond anvil cell.High Pressure Research,18-27.
MLA Chaoshuai Zhao,et al."SrB4O7:Sm2+: an optical sensor reflecting non-hydrostatic pressure at high-temperature and/or high pressure in a diamond anvil cell".High Pressure Research (2017):18-27.

入库方式: OAI收割

来源:地球化学研究所

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