Oxidative destruction of chlorobenzene and o-dichlorobenzene on a highly active catalyst: MnOx/TiO2-Al2O3
文献类型：期刊论文
| 作者 | Liu, Y; Wei, ZB; Feng, ZC; Luo, MF; Ying, PL; Li, C |
| 刊名 | journal of catalysis
 |
| 出版日期 | 2001-08-15 |
| 卷号 | 202期号:1页码:200-204 |
| 关键词 | PCDD/PCDF chlorobenzene o-dichlorobenzene oxidation supported manganese oxide catalyst TiO2-modified Al2O3 supports TPR |
| 英文摘要 | a highly active catalyst, mnox/tio2-al2o3, was prepared by impregnating mnox species on tio2-modified al2o3. the tio2 species in tio2-al2o3 support is in a monolayer dispersion, and the mnox species is again highly dispersed on tio2-al2o3 support. the total oxidation of chlorobenzene and o-dichlorobenzene on mnox/tio2-al2o3 catalyst can be achieved at 300 degreesc and 250 degreesc respectively, at the space velocity of 8000 h(-1). the activity of mnox/tio2-al2o3 catalyst (mn loading 11.2 wt%) is gradually increased in the first 10-20 h and then keeps stable at least for the measured 52 h at 16,000 h(-1). furthermore, no chlorinated organic byproducts are detected in the effluent during the oxidative destruction of chlorobenzene and o-dichlorobenzene. it is proposed that the partially chlorinated and highly dispersed manganese oxide on a monolayer tio2-modified al2o3 is responsible for the high and stable activity for the total oxidation of chlorinated aromatics. (c) 2001 academic press. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | ray photoelectron-spectroscopy ; manganese oxide catalysts ; organic-compounds ; photocatalytic degradation ; polychlorinated-biphenyls ; 4-chlorobenzoic acid ; chemical-state ; 1,2-dichlorobenzene ; hydrodechlorination ; decomposition |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000170493800021 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/91279]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Y,Wei, ZB,Feng, ZC,et al. Oxidative destruction of chlorobenzene and o-dichlorobenzene on a highly active catalyst: MnOx/TiO2-Al2O3[J]. journal of catalysis,2001,202(1):200-204. |
| APA | Liu, Y,Wei, ZB,Feng, ZC,Luo, MF,Ying, PL,&Li, C.(2001).Oxidative destruction of chlorobenzene and o-dichlorobenzene on a highly active catalyst: MnOx/TiO2-Al2O3.journal of catalysis,202(1),200-204. |
| MLA | Liu, Y,et al."Oxidative destruction of chlorobenzene and o-dichlorobenzene on a highly active catalyst: MnOx/TiO2-Al2O3".journal of catalysis 202.1(2001):200-204. |
入库方式： OAI收割
来源：大连化学物理研究所
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