Characterization of aluminosilicate zeolites by UV Raman spectroscopy
文献类型：期刊论文
| 作者 | Yu, Y; Xiong, G; Li, C; Xiao, FS |
| 刊名 | microporous and mesoporous materials
 |
| 出版日期 | 2001-07-01 |
| 卷号 | 46期号:1页码:23-34 |
| 关键词 | UV Raman spectroscopy visible Raman spectroscopy aluminosilicate zeolites crystallization mechanism |
| 英文摘要 | a series of aluminosilicate zeolites are characterized by uv raman spectroscopy for the first time, and uv raman spectra of various zeolites give strong and clear bands with high resolution, while conventional raman spectra of these zeolites are difficult to obtain because of a strong background fluorescence. additionally, these zeolites show several new bands in uv raman spectroscopy. a summary of these uv raman spectra over various zeolites suggests that the bands at 470-530, 370-430, 290-410, and 220-280 cm(-1) can be assigned to the bending modes of 4-, 5-, 6-, and 8-membered rings of aluminosilicate zeolites, respectively. furthermore, it is found that the band intensity of zeolites in uv raman spectroscopy is dependent on the si/al ratio. moreover, the uv raman spectra of crystallization, for zeolite x at various times show that, in the initial stage of crystallization, the 4-membered rings (510 cm(-1)) interconnect each other to form beta -cages with 6-membered rings (390 cm(-1)), which further crystallize to zeolite x. (c) 2001 elsevier science b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | faujasitic zeolites ; molecular-sieve ; coke formation ; gamma-alumina ; si/al ratio ; framework ; spectra ; crystallization ; catalysts ; molybdate |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000169687900003 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/92099]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Jilin Univ, Dept Chem, Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Y,Xiong, G,Li, C,et al. Characterization of aluminosilicate zeolites by UV Raman spectroscopy[J]. microporous and mesoporous materials,2001,46(1):23-34. |
| APA | Yu, Y,Xiong, G,Li, C,&Xiao, FS.(2001).Characterization of aluminosilicate zeolites by UV Raman spectroscopy.microporous and mesoporous materials,46(1),23-34. |
| MLA | Yu, Y,et al."Characterization of aluminosilicate zeolites by UV Raman spectroscopy".microporous and mesoporous materials 46.1(2001):23-34. |
入库方式： OAI收割
来源：大连化学物理研究所
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