Analysis of phenols by high-performance liquid chromatography with pre-column derivatization by 2-(9-carbazole)-ethyl-chloroformate
文献类型：期刊论文
| 作者 | Zhang, L; Zhang, LH; Zhang, WB; Zhang, YK |
| 刊名 | analytica chimica acta
 |
| 出版日期 | 2005-07-06 |
| 卷号 | 543期号:1-2页码:52-57 |
| 关键词 | 2-(9-carbazole)-ethyl-chloroformate fluorescence derivatization high-performance liquid chromatography phenols |
| ISSN号 | 0003-2670 |
| 产权排序 | 1;1 |
| 通讯作者 | 张玉奎 |
| 英文摘要 | 2-(9-carbazole)-ethyl-chloroformate (ceoc), a novel pre-column fluorescence labeling reagent, has been synthesized and applied for the derivatization of phenols. taken phenol, p-chlorophenol, 2,5-dimethylphenol, 2,4-dichlorophenol and 1,4-dihydroxybenzene as testing standards, the effects of derivatization conditions, such as ph of borate buffer, reaction time and fluorescent tagging reagent concentration, have been systematically studied. under the optimized conditions, ceoc reacts readily with the phenols to form stable derivatives with excitation and emission wavelengths, respectively, at 293 and 360 nm. the single step derivatization reaction could be finished within 20 min even at room temperature. such a method has been successfully applied to the analysis of phenols in printing ink by high-performance liquid chromatography. (c) 2005 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | solid-phase extraction ; gas-chromatography ; p-cresol ; mass-spectrometry ; labeling reagent ; 4-(4,5-diphenyl-1h-imidazol-2-yl)benzoyl chloride ; chemiluminescence detection ; fluorescence detection ; urinary phenol ; bisphenol-a |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000229953300008 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/92303]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, L,Zhang, LH,Zhang, WB,et al. Analysis of phenols by high-performance liquid chromatography with pre-column derivatization by 2-(9-carbazole)-ethyl-chloroformate[J]. analytica chimica acta,2005,543(1-2):52-57. |
| APA | Zhang, L,Zhang, LH,Zhang, WB,&Zhang, YK.(2005).Analysis of phenols by high-performance liquid chromatography with pre-column derivatization by 2-(9-carbazole)-ethyl-chloroformate.analytica chimica acta,543(1-2),52-57. |
| MLA | Zhang, L,et al."Analysis of phenols by high-performance liquid chromatography with pre-column derivatization by 2-(9-carbazole)-ethyl-chloroformate".analytica chimica acta 543.1-2(2005):52-57. |
入库方式： OAI收割
来源：大连化学物理研究所
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