Synthesis of zeolite NaA membranes with high permeance under microwave radiation on mesoporous-layer-modified macroporous substrates for gas separation
文献类型:期刊论文
作者 | Chen, XB; Yang, WS; Liu, J; Lin, LW |
刊名 | journal of membrane science
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出版日期 | 2005-06-15 |
卷号 | 255期号:1-2页码:201-211 |
关键词 | inorganic membranes gas separations membrane preparation and structure macroporous and mesoporous substrate microwave heating |
产权排序 | 1;1 |
通讯作者 | 杨维慎 |
英文摘要 | this article reported the naa zeolite membranes with high permeance synthesized with microwave heating method under different conditions: (1) on a macroporous substrate in gel, (11) on a mesoporous/macroporous (top-mesoporous-layer-modified macroporous) substrate in gel, and (111) on a mesoporous/macroporous substrate in sol. in general, the h-2 permeance of the naa membranes by microwave heating in gel was usually at the level of 10(-6) mol s(-1) m(-2) pa-1, much higher than that by the conventional hydrothermal synthesis. at similar h-2/c3h8 permselectivity. on the substrate modified mesoporous top layer, the h-2 permeance of the naa membranes by microwave heating in gel or sol was further enhanced, while maintaining comparable h-2/c3h8 permselectivity, due to the prevention of penetration of the reagent into the pores of the macroporous substrate. meanwhile, the synthesis took less time in sol than in gel on the mesoporous/macroporous substrate. the naa membranes synthesized in sol had larger permeance than those in gel and underwent transformation in shorter time. the permeation of c3h8 suggested that there existed unwanted intercrystalline pores or defects in the membranes. © 2005 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; technology ; physical sciences |
类目[WOS] | engineering, chemical ; polymer science |
研究领域[WOS] | engineering ; polymer science |
关键词[WOS] | permeation properties ; composite membranes ; liquid-mixtures ; pervaporation ; growth |
收录类别 | SCI |
原文出处 | true |
语种 | 英语 |
WOS记录号 | WOS:000229517500021 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/92365] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, XB,Yang, WS,Liu, J,et al. Synthesis of zeolite NaA membranes with high permeance under microwave radiation on mesoporous-layer-modified macroporous substrates for gas separation[J]. journal of membrane science,2005,255(1-2):201-211. |
APA | Chen, XB,Yang, WS,Liu, J,&Lin, LW.(2005).Synthesis of zeolite NaA membranes with high permeance under microwave radiation on mesoporous-layer-modified macroporous substrates for gas separation.journal of membrane science,255(1-2),201-211. |
MLA | Chen, XB,et al."Synthesis of zeolite NaA membranes with high permeance under microwave radiation on mesoporous-layer-modified macroporous substrates for gas separation".journal of membrane science 255.1-2(2005):201-211. |
入库方式: OAI收割
来源:大连化学物理研究所
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