Highly efficient route to diselenides from the reactions of imines and selenium in the presence of carbon monoxide and water
文献类型：期刊论文
| 作者 | Zhao, XD; Yu, ZK; Zeng, FL; Chen, JZ; Wu, XW; Wu, SZ; Xiao, WJ; Zheng, ZY |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2005-05-01 |
| 卷号 | 347期号:6页码:877-882 |
| 关键词 | carbon monoxide diselenation diselenides imines selenium |
| 产权排序 | 1;1 |
| 通讯作者 | 余正坤 |
| 英文摘要 | reactions of selenium with imines ((rrc)-c-1=nr2) of aldehydes and ketones in the presence of carbon monoxide, water and triethylamine lead to reductive selenation, on aerobic work-up, to afford symmetrical diselenides ((rrchse)-c-1)(2) in good to excellent yields. the proposed mechanism suggests that both in situ generated carbonyl selenide (seco) and hydrogen selenide (h2se) are involved in the reaction. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, applied ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | unsymmetrical diorganyl selenides ; functionalized diselenides ; chemoselective synthesis ; symmetrical diselenides ; aromatic-aldehydes ; alkyl-halides ; selenocysteine derivatives ; reductive selenation ; convenient synthesis ; organic diselenides |
| 收录类别 | SCI ; IC |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000229345400021 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/92547]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, XD,Yu, ZK,Zeng, FL,et al. Highly efficient route to diselenides from the reactions of imines and selenium in the presence of carbon monoxide and water[J]. advanced synthesis & catalysis,2005,347(6):877-882. |
| APA | Zhao, XD.,Yu, ZK.,Zeng, FL.,Chen, JZ.,Wu, XW.,...&Zheng, ZY.(2005).Highly efficient route to diselenides from the reactions of imines and selenium in the presence of carbon monoxide and water.advanced synthesis & catalysis,347(6),877-882. |
| MLA | Zhao, XD,et al."Highly efficient route to diselenides from the reactions of imines and selenium in the presence of carbon monoxide and water".advanced synthesis & catalysis 347.6(2005):877-882. |
入库方式： OAI收割
来源：大连化学物理研究所
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