Complete hydrodechlorination of chlorobenzene and its derivatives over supported nickel catalysts under liquid phase conditions
文献类型：期刊论文
| 作者 | Wu, WH; Xu, J; Ohnishi, R |
| 刊名 | applied catalysis b-environmental
 |
| 出版日期 | 2005-09-01 |
| 卷号 | 60期号:1-2页码:129-137 |
| 关键词 | hydrodechlorination substituted chlorobenzenes polychlorinated benzenes nickel carbon substituent effect |
| 产权排序 | 1;1 |
| 通讯作者 | 徐杰 |
| 英文摘要 | liquid phase hydrodechlorination of chlorobenzene was studied over ni/active carbon (ni/ac), ni/gamma-al2o3, ni/sio2 and raney ni. the complete hydrodechlorination of chlorobenzene was realized at 333-343 k on ni/ac under hydrogen atmosphere of 1.0 mpa in the presence of alkaline hydroxide. aryl halides, three chlorotoluenes (o-, m- and p-), three chloroanilines, three chlorobenzotrifluorides, three dichlorobenzenes and two trichlorobenzenes (1,2,3- and 1,2,4-) were also completely hydrodechlorinated under the similar conditions. chlorobenzene derivatives having either an electron-donating group or an electron-withdrawing group decreased their reactivities with respect to the unsubstituted chlorobenzene. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, environmental ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | noble-metal catalysts ; mild conditions ; chlorinated benzenes ; surface-structure ; hydrodehalogenation ; carbon ; 1,2,4-trichlorobenzene ; palladium ; halides ; hydrogenolysis |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000232328900014 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/92581]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Japan Sci & Technol Agcy, Kawaguchi 3320012, Japan |
| 推荐引用方式 GB/T 7714 | Wu, WH,Xu, J,Ohnishi, R. Complete hydrodechlorination of chlorobenzene and its derivatives over supported nickel catalysts under liquid phase conditions[J]. applied catalysis b-environmental,2005,60(1-2):129-137. |
| APA | Wu, WH,Xu, J,&Ohnishi, R.(2005).Complete hydrodechlorination of chlorobenzene and its derivatives over supported nickel catalysts under liquid phase conditions.applied catalysis b-environmental,60(1-2),129-137. |
| MLA | Wu, WH,et al."Complete hydrodechlorination of chlorobenzene and its derivatives over supported nickel catalysts under liquid phase conditions".applied catalysis b-environmental 60.1-2(2005):129-137. |
入库方式： OAI收割
来源：大连化学物理研究所
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