中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Preparation and characterization of multi-walled carbon nanotubes supported PtRu catalysts for proton exchange membrane fuel cells

文献类型:期刊论文

作者Liang, YM; Zhang, HM; Yi, BL; Zhang, ZH; Tan, ZC
刊名carbon
出版日期2005-12-01
卷号43期号:15页码:3144-3152
关键词carbon nanotubes chemical treatment temperature programmed desorption catalytic properties surface oxygen complexes
产权排序1;1
通讯作者张华民
英文摘要a series of ptru nanocomposites supported on h2o2-oxidized multi-walled carbon nanotubes (mwcnts) were synthesized via two chemical reduction methods - one used aqueous formaldehyde (hcho method) and the other used ethylene glycol (eg method) as the reducing agents. the effects of the solvents (water and ethylene glycol) and the surface composition of the mwcnts on the deposition and the dispersion of the metal particles were investigated using n-2 adsorption. tem. icp-aes. ftir and tpd. the wetting heats of the mwcnts in corresponding solvents were also measured. the characterizations suggest that combination of the surface chemistry of the mwcnts with the solvents decides the deposition and the dispersion of the metal nanoparticles. these nanocomposites were evaluated as proton exchange membrane fuel cell anode catalyts for oxidation of 50 ppm co contaminated hydrogen and compared with a commercial ptru/c catalyst. the data reveal superior performances for the nanocomposites prepared by the eg method to those by the hcho method and even to that for tile commercial analogue. structure performance relationship of the nanocomposites was also studied. (c) 2005 elsevier ltd. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, physical ; materials science, multidisciplinary
研究领域[WOS]chemistry ; materials science
关键词[WOS]activated carbon ; chemical-modification ; anode catalyst ; platinum ; electrocatalysts ; methanol ; acid ; impregnation ; performance ; sn
收录类别SCI
原文出处true
语种英语
WOS记录号WOS:000233077400010
公开日期2010-11-30
源URL[http://159.226.238.44/handle/321008/92593]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Proton Exchange Membrane Fuel Cell Key Mat & Tech, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Mat Thermochem Lab, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Liang, YM,Zhang, HM,Yi, BL,et al. Preparation and characterization of multi-walled carbon nanotubes supported PtRu catalysts for proton exchange membrane fuel cells[J]. carbon,2005,43(15):3144-3152.
APA Liang, YM,Zhang, HM,Yi, BL,Zhang, ZH,&Tan, ZC.(2005).Preparation and characterization of multi-walled carbon nanotubes supported PtRu catalysts for proton exchange membrane fuel cells.carbon,43(15),3144-3152.
MLA Liang, YM,et al."Preparation and characterization of multi-walled carbon nanotubes supported PtRu catalysts for proton exchange membrane fuel cells".carbon 43.15(2005):3144-3152.

入库方式: OAI收割

来源:大连化学物理研究所

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