Preparation and characterization of multi-walled carbon nanotubes supported PtRu catalysts for proton exchange membrane fuel cells
文献类型:期刊论文
作者 | Liang, YM; Zhang, HM; Yi, BL; Zhang, ZH; Tan, ZC |
刊名 | carbon
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出版日期 | 2005-12-01 |
卷号 | 43期号:15页码:3144-3152 |
关键词 | carbon nanotubes chemical treatment temperature programmed desorption catalytic properties surface oxygen complexes |
产权排序 | 1;1 |
通讯作者 | 张华民 |
英文摘要 | a series of ptru nanocomposites supported on h2o2-oxidized multi-walled carbon nanotubes (mwcnts) were synthesized via two chemical reduction methods - one used aqueous formaldehyde (hcho method) and the other used ethylene glycol (eg method) as the reducing agents. the effects of the solvents (water and ethylene glycol) and the surface composition of the mwcnts on the deposition and the dispersion of the metal particles were investigated using n-2 adsorption. tem. icp-aes. ftir and tpd. the wetting heats of the mwcnts in corresponding solvents were also measured. the characterizations suggest that combination of the surface chemistry of the mwcnts with the solvents decides the deposition and the dispersion of the metal nanoparticles. these nanocomposites were evaluated as proton exchange membrane fuel cell anode catalyts for oxidation of 50 ppm co contaminated hydrogen and compared with a commercial ptru/c catalyst. the data reveal superior performances for the nanocomposites prepared by the eg method to those by the hcho method and even to that for tile commercial analogue. structure performance relationship of the nanocomposites was also studied. (c) 2005 elsevier ltd. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, physical ; materials science, multidisciplinary |
研究领域[WOS] | chemistry ; materials science |
关键词[WOS] | activated carbon ; chemical-modification ; anode catalyst ; platinum ; electrocatalysts ; methanol ; acid ; impregnation ; performance ; sn |
收录类别 | SCI |
原文出处 | true |
语种 | 英语 |
WOS记录号 | WOS:000233077400010 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/92593] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Proton Exchange Membrane Fuel Cell Key Mat & Tech, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Mat Thermochem Lab, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Liang, YM,Zhang, HM,Yi, BL,et al. Preparation and characterization of multi-walled carbon nanotubes supported PtRu catalysts for proton exchange membrane fuel cells[J]. carbon,2005,43(15):3144-3152. |
APA | Liang, YM,Zhang, HM,Yi, BL,Zhang, ZH,&Tan, ZC.(2005).Preparation and characterization of multi-walled carbon nanotubes supported PtRu catalysts for proton exchange membrane fuel cells.carbon,43(15),3144-3152. |
MLA | Liang, YM,et al."Preparation and characterization of multi-walled carbon nanotubes supported PtRu catalysts for proton exchange membrane fuel cells".carbon 43.15(2005):3144-3152. |
入库方式: OAI收割
来源:大连化学物理研究所
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