In situ high temperature X-ray diffraction studies of mixed ionic and electronic conducting perovskite-type membranes
文献类型:期刊论文
作者 | Wang, HH; Tablet, S; Yang, WS; Caro, R |
刊名 | materials letters
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出版日期 | 2005-12-01 |
卷号 | 59期号:28页码:3750-3755 |
关键词 | perovskite mixed conductor oxygen separation POM membrane |
产权排序 | 2;3 |
通讯作者 | 王海辉 |
英文摘要 | phase structure and stability of three typical mixed ionic and electronic conducting perovskite-type membranes, srco0.8fe0.2o3-delta (scf), ba0.5sr0.5co0.8fe0.2o3-delta (bscf) and baco0.4fe0.4zr0.2o3-delta (bcfz) were studied by in situ high temperature x-ray diffraction at temperatures from 303 to 1273 k and under different atmospheres (air, 2% o-2 in ar and pure ar) at 1173 k. by analyzing their lattice parameters the thermal expansion coefficients (tecs) of bscf, scf and bczf are obtained to be 11.5 x 10(-6) k-1, 17.9 x 10(-6) k-1 and 10.3 x 10(-6) k-1, respectively. a relationship between phase stability and tec was proposed: the higher is the tec, the lower is the operation stability of the perovskite materials. (c) 2005 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; technology ; physical sciences |
类目[WOS] | materials science, multidisciplinary ; physics, applied |
研究领域[WOS] | materials science ; physics |
关键词[WOS] | partial oxidation ; oxygen permeation ; methane ; ba0.5sr0.5co0.8fe0.2o3-delta ; reactor ; syngas ; separation ; oxides |
收录类别 | SCI |
原文出处 | true |
语种 | 英语 |
WOS记录号 | WOS:000232514200045 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/92613] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Univ Hannover, Inst Phys Chem & Electrochem, D-30167 Hannover, Germany 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, HH,Tablet, S,Yang, WS,et al. In situ high temperature X-ray diffraction studies of mixed ionic and electronic conducting perovskite-type membranes[J]. materials letters,2005,59(28):3750-3755. |
APA | Wang, HH,Tablet, S,Yang, WS,&Caro, R.(2005).In situ high temperature X-ray diffraction studies of mixed ionic and electronic conducting perovskite-type membranes.materials letters,59(28),3750-3755. |
MLA | Wang, HH,et al."In situ high temperature X-ray diffraction studies of mixed ionic and electronic conducting perovskite-type membranes".materials letters 59.28(2005):3750-3755. |
入库方式: OAI收割
来源:大连化学物理研究所
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