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Reaction path for oxidation of ethylene to acetic acid over Pd/WO3-ZrO2 in the presence of water

文献类型:期刊论文

作者Chu, WL; Ooka, Y; Kamiya, Y; Okuhara, T
刊名catalysis letters
出版日期2005-06-01
卷号101期号:3-4页码:225-228
关键词ethylene oxidation acetic acid acetaldehyde reaction path Pd/WO3-ZrO2 Wacker-type reaction
产权排序2;1
通讯作者楚文玲
英文摘要pd-supported on wo3-zro2 (w/zr atomic ratio=0.2) calcined at 1073 k was found to be highly active and selective for gas-phase oxidation of ethylene to acetic acid in the presence of water at 423 k and 0.6 mpa. contact time dependence demonstrated that acetic acid is formed via acetaldehyde formed by a wacker-type reaction, not through ethanol by hydration of ethylene.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
收录类别SCI
原文出处true
语种英语
WOS记录号WOS:000229511400016
公开日期2010-11-30
源URL[http://159.226.238.44/handle/321008/93295]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Hokkaido Univ, Grad Sch Environm Earth Sci, Sapporo, Hokkaido 0600810, Japan
2.Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Chu, WL,Ooka, Y,Kamiya, Y,et al. Reaction path for oxidation of ethylene to acetic acid over Pd/WO3-ZrO2 in the presence of water[J]. catalysis letters,2005,101(3-4):225-228.
APA Chu, WL,Ooka, Y,Kamiya, Y,&Okuhara, T.(2005).Reaction path for oxidation of ethylene to acetic acid over Pd/WO3-ZrO2 in the presence of water.catalysis letters,101(3-4),225-228.
MLA Chu, WL,et al."Reaction path for oxidation of ethylene to acetic acid over Pd/WO3-ZrO2 in the presence of water".catalysis letters 101.3-4(2005):225-228.

入库方式: OAI收割

来源:大连化学物理研究所

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