Reaction path for oxidation of ethylene to acetic acid over Pd/WO3-ZrO2 in the presence of water
文献类型:期刊论文
作者 | Chu, WL; Ooka, Y; Kamiya, Y; Okuhara, T |
刊名 | catalysis letters
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出版日期 | 2005-06-01 |
卷号 | 101期号:3-4页码:225-228 |
关键词 | ethylene oxidation acetic acid acetaldehyde reaction path Pd/WO3-ZrO2 Wacker-type reaction |
产权排序 | 2;1 |
通讯作者 | 楚文玲 |
英文摘要 | pd-supported on wo3-zro2 (w/zr atomic ratio=0.2) calcined at 1073 k was found to be highly active and selective for gas-phase oxidation of ethylene to acetic acid in the presence of water at 423 k and 0.6 mpa. contact time dependence demonstrated that acetic acid is formed via acetaldehyde formed by a wacker-type reaction, not through ethanol by hydration of ethylene. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
收录类别 | SCI |
原文出处 | true |
语种 | 英语 |
WOS记录号 | WOS:000229511400016 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/93295] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Hokkaido Univ, Grad Sch Environm Earth Sci, Sapporo, Hokkaido 0600810, Japan 2.Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Chu, WL,Ooka, Y,Kamiya, Y,et al. Reaction path for oxidation of ethylene to acetic acid over Pd/WO3-ZrO2 in the presence of water[J]. catalysis letters,2005,101(3-4):225-228. |
APA | Chu, WL,Ooka, Y,Kamiya, Y,&Okuhara, T.(2005).Reaction path for oxidation of ethylene to acetic acid over Pd/WO3-ZrO2 in the presence of water.catalysis letters,101(3-4),225-228. |
MLA | Chu, WL,et al."Reaction path for oxidation of ethylene to acetic acid over Pd/WO3-ZrO2 in the presence of water".catalysis letters 101.3-4(2005):225-228. |
入库方式: OAI收割
来源:大连化学物理研究所
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