The observation of quantum bottleneck states
文献类型：期刊论文
| 作者 | Skodje, RT; Yang, XM |
| 刊名 | international reviews in physical chemistry
 |
| 出版日期 | 2004-04-01 |
| 卷号 | 23期号:2页码:253-287 |
| 通讯作者 | rex t.skodje |
| 英文摘要 | the concept of quantum bottleneck states near reaction barriers is essential to the elucidation of chemical reaction rates and reaction dynamics. recent studies of the dynamics of simple gas-phase chemical reactions have revealed that the transition state controls the detailed observable characteristics of a reaction to a far greater degree than was generally imagined. however, observation of such quantum bottleneck states is extremely difficult. in this article, we provide a review of the current status of observing these quantum bottleneck states in both bimolecular and unimolecular reactions, providing an updated picture of the concept of quantum bottleneck states in chemical reactions. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | quantized transition-states ; differential cross-sections ; hydrogen-exchange reaction ; chemical-reaction ; reactive scattering ; unimolecular decomposition ; reaction probabilities ; spectral quantization ; reaction dynamics ; molecular-beam |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000224279800003 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/97213]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA 2.Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Skodje, RT,Yang, XM. The observation of quantum bottleneck states[J]. international reviews in physical chemistry,2004,23(2):253-287. |
| APA | Skodje, RT,&Yang, XM.(2004).The observation of quantum bottleneck states.international reviews in physical chemistry,23(2),253-287. |
| MLA | Skodje, RT,et al."The observation of quantum bottleneck states".international reviews in physical chemistry 23.2(2004):253-287. |
入库方式： OAI收割
来源：大连化学物理研究所
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