Reversal of predominant enantioselectivity in the asymmetric alkynylation reaction using sulfamide-amine alcohols
文献类型：期刊论文
| 作者 | Mao, Jincheng; Zhang, Zhanjin; Wan, Boshun; Wu, Fan; Lu, Shiwei |
| 刊名 | catalysis communications
 |
| 出版日期 | 2006-08-01 |
| 卷号 | 7期号:8页码:550-553 |
| 关键词 | reversal of stereochemistry enantioselective alkynylzinc addition L-proline propargylic alcohols aldehydes |
| 产权排序 | 1;1 |
| 通讯作者 | 万伯顺 |
| 英文摘要 | the change of substituent in the backbone of l-proline-derived sulfamide-amine alcohol ligand 3 provides chiral propargylic alcohols with the opposite configurations in significant enantioselectivities in the asymmetric addition of phenylacetylene to aldehydes. meanwhile, the ligand 3 in combination with ti((opr)-pr-i)(4) could also afford the products with opposite absolute configuration in high yields. (c) 2006 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | aromatic-aldehydes ; phenylacetylene addition ; diethylzinc ; ligands ; alkynylzinc ; catalysts ; ketones ; binol |
| 收录类别 | SCI ; IC ; CCR |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000238799500008 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/97239]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Grp 202, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Mao, Jincheng,Zhang, Zhanjin,Wan, Boshun,et al. Reversal of predominant enantioselectivity in the asymmetric alkynylation reaction using sulfamide-amine alcohols[J]. catalysis communications,2006,7(8):550-553. |
| APA | Mao, Jincheng,Zhang, Zhanjin,Wan, Boshun,Wu, Fan,&Lu, Shiwei.(2006).Reversal of predominant enantioselectivity in the asymmetric alkynylation reaction using sulfamide-amine alcohols.catalysis communications,7(8),550-553. |
| MLA | Mao, Jincheng,et al."Reversal of predominant enantioselectivity in the asymmetric alkynylation reaction using sulfamide-amine alcohols".catalysis communications 7.8(2006):550-553. |
入库方式： OAI收割
来源：大连化学物理研究所
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