Observing the stereodynamics of chemical reactions using randomly oriented molecular beams
文献类型:期刊论文
作者 | Gustafsson, M; Skodje, RT; Zhang, JY; Dai, DX; Harich, SA; Wang, XY; Yang, XM |
刊名 | journal of chemical physics
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出版日期 | 2006-06-28 |
卷号 | 124期号:24页码:241105-1-241105-4 |
产权排序 | 2;3 |
通讯作者 | rex t.skodje ; 杨学明 |
英文摘要 | a new method is demonstrated to study the stereodynamics of simple chemical reactions that does not require the use of oriented (or aligned) molecular beams or measurements of the orientation state of product molecules. instead, it is shown that by numerically combining accurate measurements of the state-to-state differential cross section for two or more rotational states of the reagent molecule, the separate contribution from the individual helicity states can be extracted. new molecular beam experiments are conducted for the d+h-2 -> hd+h reaction that confirm the validity of the method. (c) 2006 american institute of physics. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | physics, atomic, molecular & chemical |
研究领域[WOS] | physics |
关键词[WOS] | reaction dynamics ; transition-states ; scattering ; stereochemistry ; reactivity |
收录类别 | SCI |
原文出处 | true |
语种 | 英语 |
WOS记录号 | WOS:000238730600005 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/97259] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan 2.Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Gustafsson, M,Skodje, RT,Zhang, JY,et al. Observing the stereodynamics of chemical reactions using randomly oriented molecular beams[J]. journal of chemical physics,2006,124(24):241105-1-241105-4. |
APA | Gustafsson, M.,Skodje, RT.,Zhang, JY.,Dai, DX.,Harich, SA.,...&Yang, XM.(2006).Observing the stereodynamics of chemical reactions using randomly oriented molecular beams.journal of chemical physics,124(24),241105-1-241105-4. |
MLA | Gustafsson, M,et al."Observing the stereodynamics of chemical reactions using randomly oriented molecular beams".journal of chemical physics 124.24(2006):241105-1-241105-4. |
入库方式: OAI收割
来源:大连化学物理研究所
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