中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Observing the stereodynamics of chemical reactions using randomly oriented molecular beams

文献类型:期刊论文

作者Gustafsson, M; Skodje, RT; Zhang, JY; Dai, DX; Harich, SA; Wang, XY; Yang, XM
刊名journal of chemical physics
出版日期2006-06-28
卷号124期号:24页码:241105-1-241105-4
产权排序2;3
通讯作者rex t.skodje ; 杨学明
英文摘要a new method is demonstrated to study the stereodynamics of simple chemical reactions that does not require the use of oriented (or aligned) molecular beams or measurements of the orientation state of product molecules. instead, it is shown that by numerically combining accurate measurements of the state-to-state differential cross section for two or more rotational states of the reagent molecule, the separate contribution from the individual helicity states can be extracted. new molecular beam experiments are conducted for the d+h-2 -> hd+h reaction that confirm the validity of the method. (c) 2006 american institute of physics.
WOS标题词science & technology ; physical sciences
类目[WOS]physics, atomic, molecular & chemical
研究领域[WOS]physics
关键词[WOS]reaction dynamics ; transition-states ; scattering ; stereochemistry ; reactivity
收录类别SCI
原文出处true
语种英语
WOS记录号WOS:000238730600005
公开日期2010-11-30
源URL[http://159.226.238.44/handle/321008/97259]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan
2.Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Gustafsson, M,Skodje, RT,Zhang, JY,et al. Observing the stereodynamics of chemical reactions using randomly oriented molecular beams[J]. journal of chemical physics,2006,124(24):241105-1-241105-4.
APA Gustafsson, M.,Skodje, RT.,Zhang, JY.,Dai, DX.,Harich, SA.,...&Yang, XM.(2006).Observing the stereodynamics of chemical reactions using randomly oriented molecular beams.journal of chemical physics,124(24),241105-1-241105-4.
MLA Gustafsson, M,et al."Observing the stereodynamics of chemical reactions using randomly oriented molecular beams".journal of chemical physics 124.24(2006):241105-1-241105-4.

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来源:大连化学物理研究所

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