A constitutive model coupling irradiation with two-phase lithiation for lithium-ion battery electrodes
文献类型：期刊论文
| 作者 | Wu H; Xie ZC; Wang Y; Zhang PP; Sun LZ; Lu CS ; Ma ZS
|
| 刊名 | PHILOSOPHICAL MAGAZINE
 |
| 出版日期 | 2019-04-18 |
| 卷号 | 99期号:8页码:992-1013 |
| ISSN号 | 1478-6435 |
| 关键词 | Lithium-ion batteries two-phase lithiation irradiation dislocation |
| DOI | 10.1080/14786435.2019.1569767 |
| 通讯作者 | Wang, Yan(ywang8@hnust.edu.cn) ; Ma, Zengsheng(zsma@xtu.edu.cn) |
| 英文摘要 | When lithium-ion batteries serve in extreme environments like space, severe irradiation might induce significant decay of the electrochemical performances and mechanical properties. In this paper, an electrochemical-irradiated constitutive model is proposed to explore the evolution of dislocation, defect and stress in electrodes during a two-phase lithiation process. The results from the analytic formulation and finite difference calculations show that, as Li intercalation proceeding, the hoop stress in the surface of a spherical particle converts from compression into tension because the large lithiation strain and plastic yielding at the front pushes out the material behind it. And the plastic flow resistance continuously increases with increasing irradiation dose result from the impediment of a defect to dislocation glide. There is a clear peak in the distribution of stress at yielding locations due to the competition between dislocations multiplication and defects annihilation. The model is meaningful for thoroughly understanding the micro-mechanism of lithiation deformation and provides a guideline for predicting their mechanical behaviours of lithium-ion batteries in unconventional environment. |
| 分类号 | 二类 |
| WOS关键词 | HIGH-CAPACITY ELECTRODE ; MOLECULAR-DYNAMICS SIMULATION ; AUSTENITIC STAINLESS-STEEL ; STACKING-FAULT TETRAHEDRON ; SIZE-DEPENDENT FRACTURE ; ELECTROCHEMICAL LITHIATION ; PLASTICITY MODEL ; DEFORMATION MICROSTRUCTURES ; DISLOCATION DYNAMICS ; MECHANICAL-BEHAVIOR |
| 资助项目 | National Natural Science Foundation of China[11872054] ; National Natural Science Foundation of China[11772164] |
| WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000460620300005 |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://dspace.imech.ac.cn/handle/311007/78435]  |
| 专题 | 力学研究所_非线性力学国家重点实验室 |
| 作者单位 | 1.{Wu, Hui、Zhang, Panpan、Sun, Lizhong、Ma, Zengsheng} Xiangtan Univ, Natl Prov Lab Special Funct Thin Film Mat, Xiangtan 411105, Hunan, Peoples R China 2.{Wu, Hui、Zhang, Panpan、Sun, Lizhong、Ma, Zengsheng} Xiangtan Univ, Sch Mat Sci & Engn, Xiangtan 411105, Hunan, Peoples R China 3.{Xie, Zhoucan} Chinese Acad Sci, Inst Mech, State Key Lab Nonlinear Mech, Beijing, Peoples R China 4.{Wang, Yan} Hunan Univ Sci & Technol, Sch Informat & Elect Engn, Xiangtan 411201, Hunan, Peoples R China 5.{Zhang, Panpan、Lu, Chunsheng} Curtin Univ, Sch Civil & Mech Engn, Perth, WA, Australia |
| 推荐引用方式 GB/T 7714 | Wu H,Xie ZC,Wang Y,et al. A constitutive model coupling irradiation with two-phase lithiation for lithium-ion battery electrodes[J]. PHILOSOPHICAL MAGAZINE,2019,99(8):992-1013. |
| APA | Wu H.,Xie ZC.,Wang Y.,Zhang PP.,Sun LZ.,...&Ma ZS.(2019).A constitutive model coupling irradiation with two-phase lithiation for lithium-ion battery electrodes.PHILOSOPHICAL MAGAZINE,99(8),992-1013. |
| MLA | Wu H,et al."A constitutive model coupling irradiation with two-phase lithiation for lithium-ion battery electrodes".PHILOSOPHICAL MAGAZINE 99.8(2019):992-1013. |
入库方式： OAI收割
来源：力学研究所
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