Atomically dispersed ruthenium species inside metal-organic frameworks: combining the high activity of atomic sites and the molecular sieving effect of mofs
文献类型：期刊论文
| 作者 | Ji, Shufang1; Chen, Yuanjun1; Zhao, Shu2; Chen, Wenxing1; Shi, Lijun3; Wang, Yu4; Dong, Juncai5; Li, Zhi1; Li, Fuwei3; Chen, Chen1 |
| 刊名 | Angewandte chemie-international edition
 |
| 出版日期 | 2019-03-22 |
| 卷号 | 58期号:13页码:4271-4275 |
| 关键词 | Cluster compounds Composites Heterogeneous catalysis Metal-organic frameworks Ruthenium |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201814182 |
| 通讯作者 | Wang, dingsheng(wangdingsheng@mail.tsinghua.edu.cn) ; Li, yadong(ydli@mail.tsinghua.edu.cn) |
| 英文摘要 | Incorporating atomically dispersed metal species into functionalized metal-organic frameworks (mofs) can integrate their respective merits for catalysis. a cage-controlled encapsulation and reduction strategy is used to fabricate single ru atoms and triatomic ru-3 clusters anchored on zif-8 (ru-1@zif-8, ru-3@zif-8). the highly efficient and selective catalysis for semi-hydrogenation of alkyne is observed. the excellent activity derives from high atom-efficiency of atomically dispersed ru active sites and hydrogen enrichment by the zif-8 shell. meanwhile, zif-8 shell serves as a novel molecular sieve for olefins to achieve absolute regioselectivity of catalyzing terminal alkynes but not internal alkynes. moreover, the size-dependent performance between ru-3@zif-8 and ru-1@zif-8 is detected in experiment and understood by quantum-chemical calculations, demonstrating a new and promising approach to optimize catalysts by controlling the number of atoms. |
| WOS关键词 | NANOPARTICLES ; SELECTIVITY ; NANOCRYSTALS ; CATALYST |
| 资助项目 | China Ministry of Science and Technology[2016YFA (0202801)] ; National Natural Science Foundation of China[21521091] ; National Natural Science Foundation of China[21390393] ; National Natural Science Foundation of China[U1463202] ; National Natural Science Foundation of China[21471089] ; National Natural Science Foundation of China[21671117] ; National Natural Science Foundation of China[91645203] ; National Natural Science Foundation of China[21590792] ; Beijing Natural Science Foundation[2184097] |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000462655400028 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | China Ministry of Science and Technology ; National Natural Science Foundation of China ; Beijing Natural Science Foundation |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2160569 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Wang, Dingsheng; Li, Yadong |
| 作者单位 | 1.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China 2.Beijing Univ Technol, Beijing Guyue New Mat Res Inst, Beijing 100124, Peoples R China 3.Chinese Acad Sci, LICP, Suzhou Res Inst, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China 5.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ji, Shufang,Chen, Yuanjun,Zhao, Shu,et al. Atomically dispersed ruthenium species inside metal-organic frameworks: combining the high activity of atomic sites and the molecular sieving effect of mofs[J]. Angewandte chemie-international edition,2019,58(13):4271-4275. |
| APA | Ji, Shufang.,Chen, Yuanjun.,Zhao, Shu.,Chen, Wenxing.,Shi, Lijun.,...&Li, Yadong.(2019).Atomically dispersed ruthenium species inside metal-organic frameworks: combining the high activity of atomic sites and the molecular sieving effect of mofs.Angewandte chemie-international edition,58(13),4271-4275. |
| MLA | Ji, Shufang,et al."Atomically dispersed ruthenium species inside metal-organic frameworks: combining the high activity of atomic sites and the molecular sieving effect of mofs".Angewandte chemie-international edition 58.13(2019):4271-4275. |
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来源：高能物理研究所
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