Structural change of metallofullerene: an easier thermal decomposition
文献类型：期刊论文
| 作者 | Zhao, Shixiong1,2; Zhang, Jun3; Guo, Xihong1,2; Qiu, Xiaohui3; Dong, Jinquan1,2; Yuan, Bingkai3; Ibrahim, Kurash4; Wang, Jiaou4; Qian, Haijie4; Zhao, Yuliang1,2 |
| 刊名 | Nanoscale
 |
| 出版日期 | 2011 |
| 卷号 | 3期号:10页码:4130-4134 |
| ISSN号 | 2040-3364 |
| DOI | 10.1039/c1nr10478k |
| 通讯作者 | Zhao, yuliang(zhaoyuliang@ihep.ac.cn) |
| 英文摘要 | We have studied for the first time the structural change of high-purity metallofullerene (gd@c(82)) upon heat treatment in an ultra-high vacuum system (10(-10) torr) and examined the decomposition product through successive analysis with ms, ir, raman, tem, eds and xps. it was found that metallofullerene (gd@c(82)) had fully collapsed at 580 degrees c which was lower than that for the complete destruction of c(60). the easier decomposition should be ascribed to the encapsulated metal in the carbon cage which could induce the deformation of the c-c bond. the analysis indicated that the broken metallofullerene (gd@c(82)) became a kind of graphite-like material with a lot of defects. the gd atoms leaked out from the carbon cage and aggregated together to form a regular arrangement. |
| 收录类别 | SCI |
| WOS关键词 | CARBON NANOTUBES ; ELECTROCHEMICAL PROPERTIES ; FULLERENE ; C-60 ; GD-AT-C-82 ; RAMAN ; SPECTROSCOPY ; TEMPERATURE ; SURFACE ; ANIONS |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| WOS类目 | Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied |
| 语种 | 英语 |
| WOS记录号 | WOS:000295618200022 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2176168 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Zhao, Yuliang |
| 作者单位 | 1.CAS, CAS Key Lab Biomed Effects Nanomat & Nanosafety, Inst High Energy Phys, Beijing 100049, Peoples R China 2.Natl Ctr Nanosci & Technol China, Beijing 100049, Peoples R China 3.Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Shixiong,Zhang, Jun,Guo, Xihong,et al. Structural change of metallofullerene: an easier thermal decomposition[J]. Nanoscale,2011,3(10):4130-4134. |
| APA | Zhao, Shixiong.,Zhang, Jun.,Guo, Xihong.,Qiu, Xiaohui.,Dong, Jinquan.,...&Sun, Baoyun.(2011).Structural change of metallofullerene: an easier thermal decomposition.Nanoscale,3(10),4130-4134. |
| MLA | Zhao, Shixiong,et al."Structural change of metallofullerene: an easier thermal decomposition".Nanoscale 3.10(2011):4130-4134. |
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来源：高能物理研究所
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