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Vacuum ultraviolet and near-infrared excited luminescence properties of ca-3(po4)(2):re3+, na+ (re=tb, yb, er, tm, and ho)

文献类型:期刊论文

作者Zhang, Jia1; Wang, Yuhua1; Guo, Linna1; Zhang, Feng1; Wen, Yan1; Liu, Bitao1; Huang, Yan2
刊名Journal of solid state chemistry
出版日期2011-08-01
卷号184期号:8页码:2178-2183
关键词Phosphor Vuv 3d pdps Upconversion
ISSN号0022-4596
DOI10.1016/j.jssc.2011.06.014
通讯作者Wang, yuhua(wyh@lzu.edu.cn)
英文摘要Tb3+, vb(3+), tm3+, er3+, and ho3+ doped ca-3(po4)(2) were synthesized by solid-state reaction, and their luminescence properties were studied by spectra techniques. tb3+-doped samples can exhibit intense green emission under vuv excitation, and the brightness for the optimal tb3+ content is comparable with that of the commercial zn2sio4:mn2+ green phosphor. under near-infrared laser excitation, the upconversion luminescence spectra of yb3+, tm3+, er3+, and ho3+ doped samples demonstrate that the red, green, and blue tricolored fluorescence could be obtained by codoping yb3+-ho3+, yb3+-er3+, and yb3+-tm3+ in ca-3(po4)(2), respectively. good white upconversion emission with cie chromaticity coordinates (0.358, 0.362) is achieved by quadri-doping yb3+-tm3+-er3+-ho3+ in ca-3(po4)(2), in which the cross-relaxation process between er3+ and tm3+, producing the d-1(2)-f-3(4) transition of tm3+, is found. the upconversion mechanisms are elucidated through the laser power dependence of the upconverted emissions and the energy level diagrams. (c) 2011 elsevier inc. all rights reserved.
WOS关键词UP-CONVERSION LUMINESCENCE ; VUV-UV EXCITATION ; PHOTOLUMINESCENCE PROPERTIES ; SPECTROSCOPIC PROPERTIES ; PHOSPHOR ; THERMOLUMINESCENCE ; NANOCRYSTALS ; GREEN ; TB3+ ; EU3+
WOS研究方向Chemistry
WOS类目Chemistry, Inorganic & Nuclear ; Chemistry, Physical
语种英语
WOS记录号WOS:000293802400041
出版者ACADEMIC PRESS INC ELSEVIER SCIENCE
URI标识http://www.irgrid.ac.cn/handle/1471x/2176211
专题高能物理研究所
通讯作者Wang, Yuhua
作者单位1.Lanzhou Univ, Dept Mat Sci, Sch Phys Sci & Technol, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Inst High Energy Phys, Lab Beijing Synchrotron Radiat, Beijing 100049, Peoples R China
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Zhang, Jia,Wang, Yuhua,Guo, Linna,et al. Vacuum ultraviolet and near-infrared excited luminescence properties of ca-3(po4)(2):re3+, na+ (re=tb, yb, er, tm, and ho)[J]. Journal of solid state chemistry,2011,184(8):2178-2183.
APA Zhang, Jia.,Wang, Yuhua.,Guo, Linna.,Zhang, Feng.,Wen, Yan.,...&Huang, Yan.(2011).Vacuum ultraviolet and near-infrared excited luminescence properties of ca-3(po4)(2):re3+, na+ (re=tb, yb, er, tm, and ho).Journal of solid state chemistry,184(8),2178-2183.
MLA Zhang, Jia,et al."Vacuum ultraviolet and near-infrared excited luminescence properties of ca-3(po4)(2):re3+, na+ (re=tb, yb, er, tm, and ho)".Journal of solid state chemistry 184.8(2011):2178-2183.

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