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New binuclear pd(ii) thioamide complexes for the heck reaction of aryl bromides

文献类型:期刊论文

作者Raja, Mathiyazhagan Ulaganatha1; Ramesh, Rengan1; Liu, Yu2
刊名Tetrahedron letters
出版日期2011-10-19
卷号52期号:42页码:5427-5430
关键词Thioamide ligand Binuclear palladium Heck reaction
ISSN号0040-4039
DOI10.1016/j.tetlet.2011.07.080
通讯作者Ramesh, rengan(ramesh_bdu@yahoo.com)
英文摘要The reaction of binucleating thioamide ligands (l(1)-l(3)) with [pdcl(2)(pph(3))(2)] in 1:2 molar ratio in methanol medium afforded a series of binuclear palladium(ii) complexes. the synthesized complexes were characterized by elemental analysis and (1)h nmr. the molecular structure of one of the complexes was established by x-ray diffraction method. the binuclear palladium(ii) thioamide complex has been shown to be an active catalyst for the heck reaction of aryl bromides with alkenes. (c) 2011 elsevier ltd. all rights reserved.
WOS关键词PALLADIUM PINCER COMPLEXES ; COUPLING REACTIONS ; ORGANIC HALIDES ; CATALYSTS ; MECHANISM ; ARYLATION ; LIGANDS ; SUZUKI
WOS研究方向Chemistry
WOS类目Chemistry, Organic
语种英语
WOS记录号WOS:000295552400004
出版者PERGAMON-ELSEVIER SCIENCE LTD
URI标识http://www.irgrid.ac.cn/handle/1471x/2176215
专题高能物理研究所
通讯作者Ramesh, Rengan
作者单位1.Bharathidasan Univ, Sch Chem, Tiruchchirappalli 620024, Tamil Nadu, India
2.Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Raja, Mathiyazhagan Ulaganatha,Ramesh, Rengan,Liu, Yu. New binuclear pd(ii) thioamide complexes for the heck reaction of aryl bromides[J]. Tetrahedron letters,2011,52(42):5427-5430.
APA Raja, Mathiyazhagan Ulaganatha,Ramesh, Rengan,&Liu, Yu.(2011).New binuclear pd(ii) thioamide complexes for the heck reaction of aryl bromides.Tetrahedron letters,52(42),5427-5430.
MLA Raja, Mathiyazhagan Ulaganatha,et al."New binuclear pd(ii) thioamide complexes for the heck reaction of aryl bromides".Tetrahedron letters 52.42(2011):5427-5430.

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来源:高能物理研究所

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