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The crystal structure of la0.7pr0.3ba2cu3od ceramic compound

文献类型:期刊论文

作者Wu, XS; Sha, H; Tan, WS; Yu, T; Hu, A; Jiang, SS; Wang, J; Ding, YF
刊名Powder diffraction
出版日期2002-03-01
卷号17期号:1页码:25-29
关键词Structure determination Rietveld analysis Powder diffraction La(0.7)rr(0.3)ba(2)cu(3)o(y)
ISSN号0885-7156
DOI10.1154/1.1408259
通讯作者Wu, xs()
英文摘要The structure of new la0.7pr0.3ba2cu3oy (lpbco) compound was obtained at room temperature from synchrotron radiation x-ray powder diffraction data and refined by rietveld technique. lpbco has an isotypical structure with yba2cu3oy (ybco). the crystal data are: la0.7pr0.3ba2cu3o6.96, mr = 716.16, orthorhombic system, space group pmmm, a = 3.9147(1) angstrom, b = 3.8672(1) angstrom, c = 11.7033(2) angstrom, v = 177.177(6) angstrom(3), z = 1, d-x = 6.714 g/cm(3); the structure was refined with 35 parameters to r-wp = 7.41%, r-p = 5.32%, and r-exp = 3.07% for 5001 step intensities. moreover, the total content of oxygen in a unit cell is refined as 6.96, which is less than that of the calculated one. we attribute the superconductivity-depression to the increase of the valence of copper. (c) 2002 international centre for diffraction data.
WOS关键词RAY-POWDER DIFFRACTION ; SUPERCONDUCTIVITY ; GD
WOS研究方向Materials Science
WOS类目Materials Science, Characterization & Testing
语种英语
WOS记录号WOS:000174403500007
出版者J C P D S-INT CENTRE DIFFRACTION DATA
URI标识http://www.irgrid.ac.cn/handle/1471x/2176351
专题高能物理研究所
通讯作者Wu, XS
作者单位1.Nanjing Univ, Inst Solid State Phys, Dept Phys, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China
2.Nanjing Univ, Ctr Adv Studies Sci & Technol Microstruct, Nanjing 210093, Peoples R China
3.Inst High Energy Phys, BSRL, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Wu, XS,Sha, H,Tan, WS,et al. The crystal structure of la0.7pr0.3ba2cu3od ceramic compound[J]. Powder diffraction,2002,17(1):25-29.
APA Wu, XS.,Sha, H.,Tan, WS.,Yu, T.,Hu, A.,...&Ding, YF.(2002).The crystal structure of la0.7pr0.3ba2cu3od ceramic compound.Powder diffraction,17(1),25-29.
MLA Wu, XS,et al."The crystal structure of la0.7pr0.3ba2cu3od ceramic compound".Powder diffraction 17.1(2002):25-29.

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来源:高能物理研究所

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