Metal-like boronic-organic frameworks: a design and computation
文献类型：期刊论文
| 作者 | Gao, Xingfa1,2; Gao, Xuejiao J.1,2 |
| 刊名 | Inorganic chemistry
 |
| 出版日期 | 2017-03-06 |
| 卷号 | 56期号:5页码:2490-2495 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/acs.inorgchem.6b02639 |
| 通讯作者 | Gao, xingfa(gaox@ihep.ac.cn) |
| 英文摘要 | Because of the lack of strong pi-interaction in their bonds connecting building units, most of the metal organic frameworks (mofs) and covalent-organic frameworks (cofs) achieved so far are insulators or wide-bandgap semiconductors. the design of metal-like frameworks based on known chemical components is a challenge. this work reports that aryl borons can be linked together through isocyanides to form stable and easily accessible low-dimensional boronic-organic frameworks (bofs). particularly, the boron atoms in the bofs behave like transition metals, forming the combined a sigma-donation and pi-backdonation bonds instead of the usual electron-sharing bonds with the isocyanide linkers. this peculiar bonding endows bofs with semimetal and narrow-bandgap semiconductor features, which are different from mofs and cofs and may be found to be useful in future nanoelectronics. the results open a door to integrating the knowledge of the donor-acceptor chemistry in the main group into materials science. |
| WOS关键词 | MAIN-GROUP CHEMISTRY ; GAUSSIAN-BASIS SETS ; COORDINATION CHEMISTRY ; HETEROCYCLIC CARBENES ; STABILIZED DICARBON ; CARBON(0) COMPOUNDS ; DIVALENT CARBON(0) ; TRANSITION-METALS ; PROTON CONDUCTION ; GROUP ELEMENTS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000395847300019 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2176696 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Gao, Xingfa |
| 作者单位 | 1.Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China 2.Chinese Acad Sci, Inst High Energy Phys, CAS Key Lab Biomed Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Xingfa,Gao, Xuejiao J.. Metal-like boronic-organic frameworks: a design and computation[J]. Inorganic chemistry,2017,56(5):2490-2495. |
| APA | Gao, Xingfa,&Gao, Xuejiao J..(2017).Metal-like boronic-organic frameworks: a design and computation.Inorganic chemistry,56(5),2490-2495. |
| MLA | Gao, Xingfa,et al."Metal-like boronic-organic frameworks: a design and computation".Inorganic chemistry 56.5(2017):2490-2495. |
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来源：高能物理研究所
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