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Two three-dimensional actinide-silver heterometallic coordination polymers based on 2,2 '-bipyridine-3,3 '-dicarboxylic acid with helical chains containing dimeric or trimeric motifs

文献类型:期刊论文

作者Zhao, Ran1,2; Mei, Lei1,2; Hu, Kong-qiu1,2; Wang, Lin1,2; Chai, Zhi-fang1,2,3,4; Shi, Wei-qun1,2
刊名European journal of inorganic chemistry
出版日期2017-03-17
期号11页码:1472-1477
关键词Heterometallic complexes Carboxylate ligands Helical structures Actinides Silver
ISSN号1434-1948
DOI10.1002/ejic.201601369
通讯作者Shi, wei-qun(shiwq@ihep.ac.cn)
英文摘要Under hydrothermal conditions, two new 3d actinide- silver (an-ag) heterometallic coordination polymers, namely, [ag(uo2)(2)(mu(2)-oh)(bpdc)(2)(h2o)(2)](n) (1) and [ag3th6(mu(3)-o)(mu(3)-oh)(mu(2)-oh)(6)(bpdc)(6)(no3)(6)center dot h2o](n) (2, h(2)bpdc = 2,2'-bipyridine- 3,3'-dicarboxylic acid), were assembled through a hardsoft recognition strategy. compounds 1 and 2 were character-ized by single-crystal x-ray diffraction, powder x-ray diffraction, and infrared spectroscopy. both compounds are constructed through the bridging of infinite polynuclear an-bpdc chiral helical chains by agi cations. compound 2 represents the first thivagi heterometallic coordination polymer. furthermore, the thermal stability and luminescence properties of 1 were studied.
WOS关键词METAL-ORGANIC FRAMEWORKS ; URANYL-ION COMPLEXES ; CRYSTAL-STRUCTURE ; HYDROTHERMAL SYNTHESIS ; MAGNETIC-PROPERTIES ; POSTSYNTHETIC REARRANGEMENT/METALATION ; BIMETALLIC URANYL ; LIGAND SYNTHESIS ; HYBRID MATERIALS ; 2,2'-BIPYRIDYL-3,3'-DICARBOXYLATE
WOS研究方向Chemistry
WOS类目Chemistry, Inorganic & Nuclear
语种英语
WOS记录号WOS:000397852200007
出版者WILEY-V C H VERLAG GMBH
URI标识http://www.irgrid.ac.cn/handle/1471x/2176727
专题高能物理研究所
通讯作者Shi, Wei-qun
作者单位1.Chinese Acad Sci, Lab Nucl Energy Chem, Inst High Energy Phys, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Key Lab Biomed Effects Nanomat & Nanosafety, Inst High Energy Phys, Beijing 100049, Peoples R China
3.Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, Suzhou 215123, Peoples R China
4.Soochow Univ, Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China
推荐引用方式
GB/T 7714
Zhao, Ran,Mei, Lei,Hu, Kong-qiu,et al. Two three-dimensional actinide-silver heterometallic coordination polymers based on 2,2 '-bipyridine-3,3 '-dicarboxylic acid with helical chains containing dimeric or trimeric motifs[J]. European journal of inorganic chemistry,2017(11):1472-1477.
APA Zhao, Ran,Mei, Lei,Hu, Kong-qiu,Wang, Lin,Chai, Zhi-fang,&Shi, Wei-qun.(2017).Two three-dimensional actinide-silver heterometallic coordination polymers based on 2,2 '-bipyridine-3,3 '-dicarboxylic acid with helical chains containing dimeric or trimeric motifs.European journal of inorganic chemistry(11),1472-1477.
MLA Zhao, Ran,et al."Two three-dimensional actinide-silver heterometallic coordination polymers based on 2,2 '-bipyridine-3,3 '-dicarboxylic acid with helical chains containing dimeric or trimeric motifs".European journal of inorganic chemistry .11(2017):1472-1477.

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