Peg/pvdf membranes for separating organosulphur compounds from n-heptane: effect of peg molecular weight
文献类型:期刊论文
作者 | Hu, Wenling1; Han, Xiaolong1; Liu, Liangliang1; Zhang, Xin1; Xue, Juanqin2; Wang, Baoyi3; Zhang, Peng3; Cao, Xingzhong3 |
刊名 | Canadian journal of chemical engineering
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出版日期 | 2017-02-01 |
卷号 | 95期号:2页码:364-371 |
关键词 | Peg composite membranes Pervaporation Desulphurization |
ISSN号 | 0008-4034 |
DOI | 10.1002/cjce.22657 |
通讯作者 | Han, xiaolong(hanxl@nwu.edu.cn) |
英文摘要 | Polyethylene glycol (peg) of three different molecular weights was used to prepare peg/pvdf composite membranes for separating organosulphur compounds from n-heptane by pervaporation. all the composite membranes were characterized by fourier transform infrared spectroscopy (ftir), scanning electron microscopy (sem), x-ray diffraction (xrd), and positron annihilation spectroscopy (pas). the effects of operating temperature, feed sulphur content, and organosulphur species on performance of peg/pvdf composite membranes with different molecular weights were investigated. when the feed organosulphur was thiophene, the fluxes decreased with an increase in peg molecular weight, however, the enrichment factors were in a different order: peg membrane with molecular weight of 35 000 exhibited the highest enrichment factor of 12.59 for thiophene at 85 degrees c. when the feed organosulphur was 2-methylthiophene or 2,5-dimethylthiophene, it was found that the peg membrane with molecular weight of 100 000 showed the highest enrichment factor. the results showed that peg molecular weight has a considerable effect on separation performance for pervaporation desulphurization. |
WOS关键词 | POLYETHYLENE-GLYCOL MEMBRANES ; FCC GASOLINE DESULFURIZATION ; DEEP DESULFURIZATION ; PERVAPORATION PERFORMANCE ; COMPOSITE MEMBRANES ; IONIC LIQUIDS ; FUELS ; EXTRACTION ; COMPONENTS ; MIXTURES |
WOS研究方向 | Engineering |
WOS类目 | Engineering, Chemical |
语种 | 英语 |
WOS记录号 | WOS:000393827600017 |
出版者 | WILEY-BLACKWELL |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2176801 |
专题 | 高能物理研究所 |
通讯作者 | Han, Xiaolong |
作者单位 | 1.Northwest Univ, Sch Chem Engn, Xian 710069, Shaanxi, Peoples R China 2.Xian Univ Architecture & Technol, Sch Met Engn, Xian 710055, Shaanxi, Peoples R China 3.Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Hu, Wenling,Han, Xiaolong,Liu, Liangliang,et al. Peg/pvdf membranes for separating organosulphur compounds from n-heptane: effect of peg molecular weight[J]. Canadian journal of chemical engineering,2017,95(2):364-371. |
APA | Hu, Wenling.,Han, Xiaolong.,Liu, Liangliang.,Zhang, Xin.,Xue, Juanqin.,...&Cao, Xingzhong.(2017).Peg/pvdf membranes for separating organosulphur compounds from n-heptane: effect of peg molecular weight.Canadian journal of chemical engineering,95(2),364-371. |
MLA | Hu, Wenling,et al."Peg/pvdf membranes for separating organosulphur compounds from n-heptane: effect of peg molecular weight".Canadian journal of chemical engineering 95.2(2017):364-371. |
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来源:高能物理研究所
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