Enhanced desulfurization performance and stability of pebax membrane by incorporating cu+ and fe2+ ions co-impregnated carbon nitride
文献类型：期刊论文
| 作者 | Ding, He1,2; Pan, Fusheng1,2; Mulalic, Ena3; Gomaa, Hassan3; Li, Weidong1,2; Yang, Hao1,2; Wu, Hong1,2; Jiang, Zhongyi1,2; Wang, Baoyi4; Cao, Xingzhong4 |
| 刊名 | Journal of membrane science
 |
| 出版日期 | 2017-03-15 |
| 卷号 | 526页码:94-105 |
| 关键词 | Facilitated transport hybrid membrane Carbon nitride nanosheets Cu+ Fe2+ Gasoline desulfurization |
| ISSN号 | 0376-7388 |
| DOI | 10.1016/j.memsci.2016.12.020 |
| 通讯作者 | Jiang, zhongyi(zhyjiang@tju.edu.cn) |
| 英文摘要 | In this study, cu+ and fe2+ ions were co-impregnated onto carbon nitride nanosheets via polydopamine chelating, and then incorporated into a pebax matrix to fabricate the facilitated transport hybrid membranes. the homogeneously dispersed nanosheets disturb the packing of pebax chains and render the hybrid membrane an appropriate free volume property. the existence of stabilizer fe2+ on cu+fe2+@cns prevents the disproportionation and oxidation of cu+, which is an efficient facilitated transport carrier for thiophene via pi-complexation in gasoline desulfurization. accordingly, the hybrid membranes exhibit superior desulfurization performance along with good stability even at high operation temperature. especially, when the content of cu+te2+@cns is 5 wt%, the membrane achieves the optimum desulfurization performance with a permeation flux of 13.42 kg/(m(2) h) (18.76% higher than that of pure pebax membrane) and an enrichment factor of 7.11 (28.80% higher than that of pure pebax membrane) under 60 degrees c for octane-thiophene model gasoline with thiophene content of 1312 ppm. besides, the membrane shows good stability in the long-term desulfurization under high operation temperature of 60 degrees c for 10 days and keeps the stability of incorporated cu+ for six months. the study offers a facile approach to enhance the carrier stability in high-performance facilitated transport membranes. |
| WOS关键词 | FACILITATED OLEFIN TRANSPORT ; HIGHLY SELECTIVE ADSORPTION ; PI-COMPLEXATION ; OLEFIN/PARAFFIN SEPARATION ; NANOCOMPOSITE MEMBRANES ; MODEL GASOLINE ; DIESEL FUELS ; FREE-VOLUME ; POLYMER ; PERVAPORATION |
| WOS研究方向 | Engineering ; Polymer Science |
| WOS类目 | Engineering, Chemical ; Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000393722800010 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2176804 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Jiang, Zhongyi |
| 作者单位 | 1.Tianjin Univ, Sch Chem Engn & Technol, Minist Educ, Key Lab Green Chem Technol, Tianjin 300072, Peoples R China 2.Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China 3.Univ Western Ontario, Dept Chem & Biochem Engn, London, ON N6A 5B9, Canada 4.Chinese Acad Sci, Inst High Energy Phys, Key Lab Nucl Radiat & Nucl Energy Technol, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ding, He,Pan, Fusheng,Mulalic, Ena,et al. Enhanced desulfurization performance and stability of pebax membrane by incorporating cu+ and fe2+ ions co-impregnated carbon nitride[J]. Journal of membrane science,2017,526:94-105. |
| APA | Ding, He.,Pan, Fusheng.,Mulalic, Ena.,Gomaa, Hassan.,Li, Weidong.,...&Zhang, Peng.(2017).Enhanced desulfurization performance and stability of pebax membrane by incorporating cu+ and fe2+ ions co-impregnated carbon nitride.Journal of membrane science,526,94-105. |
| MLA | Ding, He,et al."Enhanced desulfurization performance and stability of pebax membrane by incorporating cu+ and fe2+ ions co-impregnated carbon nitride".Journal of membrane science 526(2017):94-105. |
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