Solvent-dependent synthesis of porous anionic uranyl-organic frameworks featuring a highly symmetrical (3,4)-connected ctn or bor topology for selective dye adsorption
文献类型：期刊论文
| 作者 | Hu, Kong-Qiu1; Jiang, Xiang2; Wang, Cong-Zhi1; Mei, Lei1; Xie, Zhen-Ni1; Tao, Wu-Qing1; Zhang, Xiao-Lin1; Chai, Zhi-Fang1; Shi, Wei-Qun1 |
| 刊名 | Chemistry-a european journal
 |
| 出版日期 | 2017-01-12 |
| 卷号 | 23期号:3页码:529-532 |
| 关键词 | Interpenetrating structures Metal-organic frameworks Morphology change Selective dye adsorption Uranyl cation |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201604225 |
| 通讯作者 | Shi, wei-qun(shiwq@ihep.ac.cn) |
| 英文摘要 | Two highly symmetrical (3,4)-connected uranylorganic frameworks (uofs) were synthesized by a judicious combination of d-3h-symmetrical triangular [uo2(coo)(3)](-) and t-d symmetrical tetrahedral tetrakis(4-carboxyphenyl)-methane (h4mtb). these two as-synthesized uofs possess similar structural units and coordination modes but totally different topological structures, namely ctn net and bor net. solvent-induced interpenetration and a morphology change are observed. the two compounds exhibit crystal transformation via a dissolution-crystallization process. adsorption experiments in ch3oh solution indicate that both of them can selectively remove positively charged dyes over negatively charged and neutral dyes. moreover, the electronic structural and bonding properties of the two compounds were systematically explored by density functional theory (dft) calculations. |
| WOS关键词 | COORDINATION POLYMER ; MAGNETIC-PROPERTIES ; HYDROGEN UPTAKE ; SOLID-STATE ; METAL ; NETWORKS ; LUMINESCENCE ; CARBOXYLATES ; TRANSITION ; SEPARATION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000393625600005 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2176808 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Shi, Wei-Qun |
| 作者单位 | 1.Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China 2.Fac Mat Sci & Chem, Wuhan 430074, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Kong-Qiu,Jiang, Xiang,Wang, Cong-Zhi,et al. Solvent-dependent synthesis of porous anionic uranyl-organic frameworks featuring a highly symmetrical (3,4)-connected ctn or bor topology for selective dye adsorption[J]. Chemistry-a european journal,2017,23(3):529-532. |
| APA | Hu, Kong-Qiu.,Jiang, Xiang.,Wang, Cong-Zhi.,Mei, Lei.,Xie, Zhen-Ni.,...&Shi, Wei-Qun.(2017).Solvent-dependent synthesis of porous anionic uranyl-organic frameworks featuring a highly symmetrical (3,4)-connected ctn or bor topology for selective dye adsorption.Chemistry-a european journal,23(3),529-532. |
| MLA | Hu, Kong-Qiu,et al."Solvent-dependent synthesis of porous anionic uranyl-organic frameworks featuring a highly symmetrical (3,4)-connected ctn or bor topology for selective dye adsorption".Chemistry-a european journal 23.3(2017):529-532. |
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来源：高能物理研究所
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