High mechanical strength in zn4b6o13 with an unique sodalite-cage structure
文献类型：期刊论文
| 作者 | Yang, Yi1,5; Jiang, Xingxing1; Gong, Pifu1,5; Molokeev, Maxim S.2,6; Li, Xiaodong3; Li, Yanchun3; Wu, Xiang4; Wu, Yicheng1; Lin, Zheshuai1,5 |
| 刊名 | Rsc advances
 |
| 出版日期 | 2017 |
| 卷号 | 7期号:4页码:2038-2043 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c6ra25752f |
| 通讯作者 | Jiang, xingxing(xxjiang@mail.ipc.ac.cn) ; Lin, zheshuai(zslin@mail.ipc.ac.cn) |
| 英文摘要 | Recently, a borate crystal zn4b6o13 (zbo) has been focused on since it exhibits novel isotropic near-zero thermal expansion behavior in a wide temperature range. in this work, the mechanical properties in zbo are studied by high-pressure x-ray diffraction and first-principles calculations. it is found that zbo possesses the highest mechanical hardness in all known borates whose mechanical properties have been measured. the very high mechanical strength in zbo mainly originates from the resistance of strong zn-o bonds to the rotation among bo4 tetrahedra in the unique sodalite-cage structure. moreover, zbo shows relatively high mechanical resistance to the axial and shear stress and exhibits high optical transparence in the ultraviolet spectral region under high pressure. benefitting from these good properties, zbo may find potential applications in high-precision optical facilities used at extreme conditions under complex environments. |
| WOS关键词 | NONLINEAR-OPTICAL CRYSTALS ; NEGATIVE LINEAR COMPRESSIBILITY ; ULTRAVIOLET REGION ; THERMAL-EXPANSION ; SINGLE-CRYSTAL ; PSEUDOPOTENTIALS ; DIFFRACTION ; PRINCIPLES ; GROWTH ; RANGE |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000393748000034 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2176845 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Jiang, Xingxing; Lin, Zheshuai |
| 作者单位 | 1.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Funct Crystals & Laser Technol, Ctr Crystal Res & Dev, Beijing 100190, Peoples R China 2.SBRAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia 3.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China 4.China Univ Geosci, State Key Lab Geol Proc & Mineral Resources, Wuhan 430074, Peoples R China 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 6.Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia |
| 推荐引用方式 GB/T 7714 | Yang, Yi,Jiang, Xingxing,Gong, Pifu,et al. High mechanical strength in zn4b6o13 with an unique sodalite-cage structure[J]. Rsc advances,2017,7(4):2038-2043. |
| APA | Yang, Yi.,Jiang, Xingxing.,Gong, Pifu.,Molokeev, Maxim S..,Li, Xiaodong.,...&Lin, Zheshuai.(2017).High mechanical strength in zn4b6o13 with an unique sodalite-cage structure.Rsc advances,7(4),2038-2043. |
| MLA | Yang, Yi,et al."High mechanical strength in zn4b6o13 with an unique sodalite-cage structure".Rsc advances 7.4(2017):2038-2043. |
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