Quasi 3d polymerization in c-60 bilayers in a fullerene solvate
文献类型：期刊论文
| 作者 | Pei, Cuiying1; Feng, Meina2,3,4; Yang, Zhenxing4; Yao, Mingguang4; Yuan, Ye1; Li, Xin1; Hu, Bingwen5; Shen, Ming5; Chen, Bin6; Sundqvist, Bertil4,7 |
| 刊名 | Carbon
 |
| 出版日期 | 2017-11-01 |
| 卷号 | 124页码:499-505 |
| ISSN号 | 0008-6223 |
| 关键词 | Solvate fullerene Polymerization High pressure Spectroscopy Synchrotron xrd |
| DOI | 10.1016/j.carbon.2017.09.010 |
| 通讯作者 | Wang, lin(wanglin@hpstar.ac.cn) |
| 英文摘要 | The polymerization of fullerenes has been an interesting topic for almost three decades. a rich polymeric phase diagram of c-60 has been drawn under a variety of pressure-temperature conditions. however, only linear or perpendicular linkages of c-60 are found in the ordered phases. here we used a unique bilayer structural solvate, c-60.1,1,2-trichloroethane (c-60.1tcan),to generate a novel quasi-3d c-60 polymer under high pressure and/or high temperature. using raman, ir spectroscopy and x-ray diffraction, we observe that the solvent molecules play a crucial role in confining the [2 + 2] cycloaddition bonds of c(60)s forming in the upper and lower layers alternately. the relatively long distance between the two bilayers restricts the covalent linkage extended in a single individual bilayer. our studies not only enrich the phase diagram of polymeric c-60, but also facilitate targeted design and synthesis of unique c-60 polymers. (c) 2017 elsevier ltd. all rights reserved. |
| WOS关键词 | HIGH-PRESSURE ; PHASE-TRANSITIONS ; HIGH-TEMPERATURE ; FILMS ; PHOTOLUMINESCENCE ; NANORODS ; MONOMER |
| WOS研究方向 | Chemistry ; Materials Science |
| WOS类目 | Chemistry, Physical ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| WOS记录号 | WOS:000412118200054 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2177127 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Wang, Lin |
| 作者单位 | 1.Ctr High Pressure Sci & Technol Adv Res, 1690 Cailun Rd, Shanghai 201203, Peoples R China 2.Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China 3.Dongguan Neutron Sci Ctr, Dongguan 523803, Guangdong, Peoples R China 4.Jilin Univ, State Key Lab Superhard Mat, Changchun 130012, Jilin, Peoples R China 5.East China Normal Univ, Shanghai Key Lab Magnet Resonance, Sch Phys & Mat Sci, Shanghai 200062, Peoples R China 6.Univ Hawaii Manoa, Hawaii Inst Geophys & Planetol, Honolulu, HI 96822 USA 7.Umea Univ, Dept Phys, S-90187 Umea, Sweden |
| 推荐引用方式 GB/T 7714 | Pei, Cuiying,Feng, Meina,Yang, Zhenxing,et al. Quasi 3d polymerization in c-60 bilayers in a fullerene solvate[J]. Carbon,2017,124:499-505. |
| APA | Pei, Cuiying.,Feng, Meina.,Yang, Zhenxing.,Yao, Mingguang.,Yuan, Ye.,...&Wang, Lin.(2017).Quasi 3d polymerization in c-60 bilayers in a fullerene solvate.Carbon,124,499-505. |
| MLA | Pei, Cuiying,et al."Quasi 3d polymerization in c-60 bilayers in a fullerene solvate".Carbon 124(2017):499-505. |
入库方式： iSwitch采集
来源：高能物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。