The effect of sr2+ on luminescence of ce3+-doped (ca,sr)(2)al2sio7
文献类型：期刊论文
| 作者 | Lin, Litian1; Shi, Rui1; Zhou, Rongfu1; Peng, Qi1; Liu, Chunmeng1; Tao, Ye2; Huang, Yan2; Dorenbos, Pieter3; Liang, Hongbin1 |
| 刊名 | Inorganic chemistry
 |
| 出版日期 | 2017-10-16 |
| 卷号 | 56期号:20页码:12476-12484 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/acs.inorgchem.7b01939 |
| 通讯作者 | Liang, hongbin(cesbin@mail.sysu.edu.cn) |
| 英文摘要 | A series of ce3+-doped (ca,sr)(2)al2sio7 phosphors with different ce3+ and ca2+/sr2+ concentrations were prepared by a high temperature solid-state reaction technique. to get insight into the structure-luminescence relationship, the impact of incorporation of sr2+ on structure of (ca,sr)(2)al2sio7 was first investigated via rietveld refinement of high quality x-ray diffraction (xrd) data, and then the vuv-uv excitation and uv-vis emission spectra of (ca,sr)(2)al2sio2:ce3+ were collected at low temperature. the results reveal that the crystal structure evolution of (ca,sr)(2)al2sio7:ce3+ has influences on band gaps and ce3+ luminescence properties including 4f-5d, (i = 1-5) transition energies, radiative lifetime, emission intensity, quantum efficiency, and thermal stability. moreover, the influence of sr2+ content on the energy of eu3+-o2- charge-transfer states (cts) in (ca,sr)(2)al2sio7:eu3+ was studied in order to construct vacuum referred binding energy (vrbe) schemes with the aim to further understand the luminescence properties of (ca,sr)(2)al2sio7:ce3+. finally, x-ray excited luminescence (xel) spectra were measured to evaluate the possibility of (ca,sr)(2)al2sio2:ce3+ as a scintillation material. |
| WOS关键词 | LIGHT-EMITTING-DIODES ; ENERGY-TRANSFER ; ELECTRONIC-STRUCTURE ; INORGANIC-COMPOUNDS ; CE3+ ; GARNET ; PHOSPHOR ; SPECTROSCOPY ; CRYSTALS ; SCINTILLATORS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000413279300044 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2177145 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Liang, Hongbin |
| 作者单位 | 1.Sun Yat Sen Univ, Sch Chem, MOE Key Lab Bioinorgan & Synthet Chem, KLGHEI Environm & Energy Chem, Guangzhou 510275, Guangdong, Peoples R China 2.Chinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100039, Peoples R China 3.Delft Univ Technol, Fac Appl Sci, Mekelweg 15, NL-2629 JB Delft, Netherlands |
| 推荐引用方式 GB/T 7714 | Lin, Litian,Shi, Rui,Zhou, Rongfu,et al. The effect of sr2+ on luminescence of ce3+-doped (ca,sr)(2)al2sio7[J]. Inorganic chemistry,2017,56(20):12476-12484. |
| APA | Lin, Litian.,Shi, Rui.,Zhou, Rongfu.,Peng, Qi.,Liu, Chunmeng.,...&Liang, Hongbin.(2017).The effect of sr2+ on luminescence of ce3+-doped (ca,sr)(2)al2sio7.Inorganic chemistry,56(20),12476-12484. |
| MLA | Lin, Litian,et al."The effect of sr2+ on luminescence of ce3+-doped (ca,sr)(2)al2sio7".Inorganic chemistry 56.20(2017):12476-12484. |
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