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Water-soluble inorganic photocatalyst for overall water splitting

文献类型:期刊论文

作者Li, Yu Hang1; Wang, Yun2; Zheng, Li Rong3; Zhao, Hui Jun2; Yang, Hua Gui1; Li, Chunzhong1
刊名Applied catalysis b-environmental
出版日期2017-07-15
卷号209页码:247-252
关键词Overall water splitting Photocatalysts Sodium molybdate salt Water-soluble inorganics
ISSN号0926-3373
DOI10.1016/j.apcatb.2017.03.001
通讯作者Yang, hua gui(hgyang@ecust.edu.cn) ; Li, chunzhong(czli@ecust.edu.cn)
英文摘要In the past 45 years, the search for semiconductors as active photocatalysts for overall water splitting has focused on insoluble materials and their hybrids. an important question is whether soluble semiconductors have the capacity for photocatalysis or similar applications. the dissolved semiconductors will lose the energy band structures for light absorption; however, the undissolved part in saturated solution can still generate electrons and holes under illumination. unfortunately, this possibility has never been realized. here we clearly demonstrate the use of a water-soluble sodium molybdate salt as an effective photocatalyst. the material can photocatalyze simultaneously the oxidation and reduction of water under band-gap irradiation. we anticipate that, as a large and traditional class of chemical compounds, the soluble semiconductors may have great potential to be applied in numerous important applications such as catalysis, photovoltaics, light emitting diodes and artificial photosynthesis. (c) 2017 elsevier b.v. all rights reserved.
WOS关键词VISIBLE-LIGHT-DRIVEN ; HYDROGEN EVOLUTION ; CATALYSTS ; NANOSTRUCTURES ; SEMICONDUCTORS ; NANOPARTICLES ; CHALLENGES ; COMPOSITE ; OXIDATION ; METALS
WOS研究方向Chemistry ; Engineering
WOS类目Chemistry, Physical ; Engineering, Environmental ; Engineering, Chemical
语种英语
WOS记录号WOS:000400584900026
出版者ELSEVIER SCIENCE BV
URI标识http://www.irgrid.ac.cn/handle/1471x/2177224
专题高能物理研究所
通讯作者Yang, Hua Gui; Li, Chunzhong
作者单位1.East China Univ Sci & Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Ultrafine Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China
2.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Southport, Qld 4222, Australia
3.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Li, Yu Hang,Wang, Yun,Zheng, Li Rong,et al. Water-soluble inorganic photocatalyst for overall water splitting[J]. Applied catalysis b-environmental,2017,209:247-252.
APA Li, Yu Hang,Wang, Yun,Zheng, Li Rong,Zhao, Hui Jun,Yang, Hua Gui,&Li, Chunzhong.(2017).Water-soluble inorganic photocatalyst for overall water splitting.Applied catalysis b-environmental,209,247-252.
MLA Li, Yu Hang,et al."Water-soluble inorganic photocatalyst for overall water splitting".Applied catalysis b-environmental 209(2017):247-252.

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来源:高能物理研究所

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