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An experimental study of the local electronic structure of b-site gallium doped bismuth ferrite powders

文献类型:期刊论文

作者Gholam, Turghunjan1; Ablat, Abduleziz1; Mamat, Mamatrishat1; Wu, Rong1; Aimidula, Aimierding1; Bake, Muhammad Ali1; Zheng, Lirong2; Wang, Jiaou2; Qian, Haijie2; Wu, Rui2
刊名Physics letters a
出版日期2017-08-05
卷号381期号:29页码:2367-2373
关键词Hydrothermal method Multiferroics X-ray absorption fine structure Bifeo3
ISSN号0375-9601
DOI10.1016/j.physleta.2017.05.007
通讯作者Ablat, abduleziz(a_ablat@hotmail.com)
英文摘要The un-doped and gallium (ga) doped multiferroic bismuth ferrite (bifeo3) compounds were successfully synthesized by the hydrothermal technique. this is then followed by a series of detailed investigations into the influence of ga doping on the structural, morphological, optical and magnetic properties of bife1_xgaxo3 (0 <= x <= 0.15). x-ray diffraction (xrd) analyses reveal that b-site doping of ga may lead to the transformation of its crystal structure from a rhombohedral with a space group of r3c to an orthorhombic with a space group of pbnm phase. the scanning electron microscope (sem) images show that doping with ga causes a significant reduction in particle size, when compared to un-doped bifeo3. x-ray absorption near-edge structure (xanes) spectra have also shown that as the substitution of ga increases, the fe k and bi l-iii-edge absorption spectra shift towards higher energy site. it also implies that doping of ga affects the local structures of both bi and fe atoms. distinct transmission band fluctuations, as shown by fourier transform infrared (ft-ir) spectra, can provide significant evidence for a transformation in crystal structure, following the increase of ga concentration. the magnetization hysteresis measurements show that the magnetization decreases when ga content is x >= 0.05. such a phenomenon mainly stems from the substitution of fe for an excessive amount of ga, resulting in reduction of both valence fluctuations and the magnetization in the bife1_xgaxo3 system. (c) 2017 elsevier b.v. all rights reserved.
WOS关键词HYDROTHERMAL SYNTHESIS ; WEAK FERROMAGNETISM ; THIN-FILMS ; BIFEO3 ; PHASE
WOS研究方向Physics
WOS类目Physics, Multidisciplinary
语种英语
WOS记录号WOS:000403986900014
出版者ELSEVIER SCIENCE BV
URI标识http://www.irgrid.ac.cn/handle/1471x/2177324
专题高能物理研究所
通讯作者Ablat, Abduleziz
作者单位1.Xinjiang Univ, Sch Phys Sci & Technol, Urumqi 830046, Peoples R China
2.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Gholam, Turghunjan,Ablat, Abduleziz,Mamat, Mamatrishat,et al. An experimental study of the local electronic structure of b-site gallium doped bismuth ferrite powders[J]. Physics letters a,2017,381(29):2367-2373.
APA Gholam, Turghunjan.,Ablat, Abduleziz.,Mamat, Mamatrishat.,Wu, Rong.,Aimidula, Aimierding.,...&Ibrahim, Kurash.(2017).An experimental study of the local electronic structure of b-site gallium doped bismuth ferrite powders.Physics letters a,381(29),2367-2373.
MLA Gholam, Turghunjan,et al."An experimental study of the local electronic structure of b-site gallium doped bismuth ferrite powders".Physics letters a 381.29(2017):2367-2373.

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