Thermodynamics of the protonation of an analogue of glyphosate, n-(phosphonomethyl)-l-proline, in aqueous solutions
文献类型：期刊论文
| 作者 | Li, Qiang1; Liu, Bijun1; Tian, Yin2; Yu, Qianhong1; Mu, Wanjun1; Wei, Hongyuan1; Wang, Dongqi3; Li, Xingliang1; Luo, Shunzhong1 |
| 刊名 | Journal of solution chemistry
 |
| 出版日期 | 2017-05-01 |
| 卷号 | 46期号:5页码:1048-1058 |
| 关键词 | Glyphosate N-(phosphonomethyl)-l-proline Protonation |
| ISSN号 | 0095-9782 |
| DOI | 10.1007/s10953-017-0620-0 |
| 通讯作者 | Tian, yin(tianyin@swip.ac.cn) ; Li, xingliang(xingliang@caep.cn) ; Luo, shunzhong(luoshzh@caep.cn) |
| 英文摘要 | N-(phosphonomethyl)-l-proline is an analogue of glyphosate. the protonation for n-(phosphonomethyl)-l-proline was studied by potentiometry, calorimetry, p-31 nmr spectroscopy and quantum chemical calculations to further understand the protonation process of glyphosate. the results confirmed that the order of successive protonation sites of totally deprotonated n-(phosphonomethyl)-l-proline are a phosphonate oxygen, amino nitrogen, and finally the carboxylate oxygen. the results can improve the understanding of the biological activity of these types of molecules in solution. |
| WOS关键词 | TRIFUNCTIONAL PHOSPHONATE ANIONS ; HYDROTHERMAL SYNTHESIS ; CRYSTAL-STRUCTURE ; CARBOXYLATE-PHOSPHONATE ; EQUILIBRIUM-CONSTANTS ; ACID ; MODEL ; NMR ; POTENTIOMETRY ; DISPERSION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000404328600003 |
| 出版者 | SPRINGER/PLENUM PUBLISHERS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2177329 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Tian, Yin; Li, Xingliang; Luo, Shunzhong |
| 作者单位 | 1.China Acad Engn Phys, Inst Nucl Phys & Chem, Mianyang 621999, Sichuan, Peoples R China 2.Southwestern Inst Phys, Chengdu 610041, Sichuan, Peoples R China 3.Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Qiang,Liu, Bijun,Tian, Yin,et al. Thermodynamics of the protonation of an analogue of glyphosate, n-(phosphonomethyl)-l-proline, in aqueous solutions[J]. Journal of solution chemistry,2017,46(5):1048-1058. |
| APA | Li, Qiang.,Liu, Bijun.,Tian, Yin.,Yu, Qianhong.,Mu, Wanjun.,...&Luo, Shunzhong.(2017).Thermodynamics of the protonation of an analogue of glyphosate, n-(phosphonomethyl)-l-proline, in aqueous solutions.Journal of solution chemistry,46(5),1048-1058. |
| MLA | Li, Qiang,et al."Thermodynamics of the protonation of an analogue of glyphosate, n-(phosphonomethyl)-l-proline, in aqueous solutions".Journal of solution chemistry 46.5(2017):1048-1058. |
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