中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Evolution of microstructural defects of tio2 nanocrystals by zr4+ or/and ge4+ doping lead to high disinfection efficiency for cwas

文献类型:期刊论文

作者Shen, Zhong1,2; Zhong, Jin-Yi2,3; Chai, Na-Na1; He, Xin1; Zang, Jian-Zheng1; Xu, Hui1; Han, Xiao-Yuan1; Zhang, Peng4
刊名Chemical physics letters
出版日期2017-06-16
卷号678页码:146-152
关键词Chemical warfare agents Decontamination Zirconium Germanium Titanium dioxide Positron annihilation lifetime spectroscopy
ISSN号0009-2614
DOI10.1016/j.cplett.2017.03.069
通讯作者Shen, zhong(shenzhong_626@163.com)
英文摘要Zr4+, ge4+ doped and co-doped tio2 nanoparticles were prepared by a 'one-pot' homogeneous precipitation method. the photocatalytic reaction kinetics of dmmp and the disinfection efficiency of hd, gd and vx on the samples were investigated. by means of a variety of characterization methods, especially the positron annihilation lifetime spectroscopy, the changes in structure and property of tio2 across doping were studied. the results show that the reasonable engineering design of novel photocatalysts in the field of cwas decontamination can be realized by adjusting the bulk-to-surface defects ratio, except for crystal structure, specific surface area, pore size distribution and light utilization. (c) 2017 elsevier b.v. all rights reserved.
WOS关键词VACANCY-TYPE DEFECTS ; POSITRON-ANNIHILATION ; PHOTOCATALYTIC ACTIVITY ; PHASE-TRANSITION ; WARFARE AGENTS ; DOPED TIO2 ; TITANIA ; DEGRADATION ; LIFETIME
WOS研究方向Chemistry ; Physics
WOS类目Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
语种英语
WOS记录号WOS:000402218100025
出版者ELSEVIER SCIENCE BV
URI标识http://www.irgrid.ac.cn/handle/1471x/2177358
专题高能物理研究所
通讯作者Shen, Zhong
作者单位1.North Western Inst Nucl Technol, POB 69, Xian 710024, Peoples R China
2.Res Inst Chem Def, POB 1043, Beijing 102205, Peoples R China
3.State Key Lab NBC Protect Civilian, POB 1043, Beijing 102205, Peoples R China
4.Chinese Acad Sci, Inst High Energy Phys, Yuquan Rd 19, Beijing 100040, Peoples R China
推荐引用方式
GB/T 7714
Shen, Zhong,Zhong, Jin-Yi,Chai, Na-Na,et al. Evolution of microstructural defects of tio2 nanocrystals by zr4+ or/and ge4+ doping lead to high disinfection efficiency for cwas[J]. Chemical physics letters,2017,678:146-152.
APA Shen, Zhong.,Zhong, Jin-Yi.,Chai, Na-Na.,He, Xin.,Zang, Jian-Zheng.,...&Zhang, Peng.(2017).Evolution of microstructural defects of tio2 nanocrystals by zr4+ or/and ge4+ doping lead to high disinfection efficiency for cwas.Chemical physics letters,678,146-152.
MLA Shen, Zhong,et al."Evolution of microstructural defects of tio2 nanocrystals by zr4+ or/and ge4+ doping lead to high disinfection efficiency for cwas".Chemical physics letters 678(2017):146-152.

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来源:高能物理研究所

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