Isolated single iron atoms anchored on n-doped porous carbon as an efficient electrocatalyst for the oxygen reduction reaction
文献类型：期刊论文
| 作者 | Chen, Yuanjun1; Ji, Shufang1; Wang, Yanggang1; Dong, Juncai2; Chen, Wenxing1; Li, Zhi1; Shen, Rongan1; Zheng, Lirong2; Zhuang, Zhongbin3,4; Wang, Dingsheng1 |
| 刊名 | Angewandte chemie-international edition
 |
| 出版日期 | 2017-06-06 |
| 卷号 | 56期号:24页码:6937-6941 |
| 关键词 | Electrocatalysts Iron Oxygen reduction reaction Porous carbons Single-atom catalysts |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201702473 |
| 通讯作者 | Wang, dingsheng(wangdingsheng@mail.tsinghua.edu.cn) ; Li, yadong(ydli@mail.tsinghua.edu.cn) |
| 英文摘要 | The development of low-cost, efficient, and stable electrocatalysts for the oxygen reduction reaction (orr) is desirable but remains a great challenge. herein, we made a highly reactive and stable isolated single-atom fe/n-doped porous carbon (isa fe/cn) catalyst with fe loading up to 2.16 wt%. the catalyst showed excellent orr performance with a half-wave potential (e-1/2) of 0.900 v, which outperformed commercial pt/c and most non-precious-metal catalysts reported to date. besides exceptionally high kinetic current density (j(k)) of 37.83 mvcm(-2) at 0.85 v, it also had a good methanol tolerance and outstanding stability. experiments demonstrated that maintaining the fe as isolated atoms and incorporating nitrogen was essential to deliver the high performance. first principle calculations further attributed the high reactivity to the high efficiency of the single fe atoms in transporting electrons to the adsorbed oh species. |
| WOS关键词 | FUEL-CELLS ; CATALYSTS ; PERFORMANCE ; GRAPHENE ; COORDINATION ; STABILITY ; COBALT |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000402523900044 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2177359 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Wang, Dingsheng; Li, Yadong |
| 作者单位 | 1.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China 2.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing, Peoples R China 3.Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China 4.Beijing Univ Chem Technol, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, Beijing 100029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Yuanjun,Ji, Shufang,Wang, Yanggang,et al. Isolated single iron atoms anchored on n-doped porous carbon as an efficient electrocatalyst for the oxygen reduction reaction[J]. Angewandte chemie-international edition,2017,56(24):6937-6941. |
| APA | Chen, Yuanjun.,Ji, Shufang.,Wang, Yanggang.,Dong, Juncai.,Chen, Wenxing.,...&Li, Yadong.(2017).Isolated single iron atoms anchored on n-doped porous carbon as an efficient electrocatalyst for the oxygen reduction reaction.Angewandte chemie-international edition,56(24),6937-6941. |
| MLA | Chen, Yuanjun,et al."Isolated single iron atoms anchored on n-doped porous carbon as an efficient electrocatalyst for the oxygen reduction reaction".Angewandte chemie-international edition 56.24(2017):6937-6941. |
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