Modulation of of the microstructure of the ag/c-based alkaline cathode via the ionomer content for a bipolar membrane fuel cell
文献类型：期刊论文
| 作者 | Xu, Xin1; Peng, Sikan1,2; Lu, Shanfu1; Gong, Jian1; Zhang, Jin1; Huang, Wanxia3; Xiang, Yan1 |
| 刊名 | Journal of power sources
 |
| 出版日期 | 2017-06-30 |
| 卷号 | 354页码:92-99 |
| 关键词 | Bipolar membrane fuel cell Ag/c Cathode catalyst layer Ionomer content Nano-ct |
| ISSN号 | 0378-7753 |
| DOI | 10.1016/j.jpowsour.2017.04.006 |
| 通讯作者 | Lu, shanfu(lusf@buaa.edu.cn) ; Xiang, yan(xiangy@buaa.edu.cn) |
| 英文摘要 | Ag/c is evaluated as a cathode catalyst for a bipolar membrane fuel cell (bpmfc). the microstructure of the cathode catalyst layer is modulated via ionomer content, and the effects on bpmfc performance are studied. when the ionomer content is increased from 10 wt% to 30 wt%, the fuel cell performance is optimized at 19.3 mw/cm(2) with an ionomer content of 20 wt%. electrochemical impedance spectroscopy (eis) and cyclic voltammetry (cv) are conducted on the catalyst layer. eis indicates that the charge transfer resistance is minimum, while cv suggests that the highest electrocatalytic activity of the catalyst is achieved with an ionomer content of 20 wt%. the microstructure of the catalyst layer is characterized using scanning electron microscopy (sem) and nanometer-scale x-ray computed tomography (nano-ct). the sem results show that excess ionomer cover on the surface of the catalyst, and the catalyst seems to form larger aggregates. nano-ct, however, produces quite different results. the reconstructed 3d image of the catalyst layer reveals that the ag/c catalyst tends to aggregate at low ionomer content. when the ionomer content is increased from 10 wt% to 30 wt%, the average diameter of the catalyst aggregation decreases from 313 nm to 210 nm. (c) 2017 elsevier b.v. all rights reserved. |
| WOS关键词 | OXYGEN REDUCTION REACTION ; RAY COMPUTED-TOMOGRAPHY ; OPTIMUM NAFION CONTENT ; CATALYST LAYER ; NM-RESOLUTION ; ELECTROLYTE ; PERFORMANCE ; CARBON ; MEDIA ; ANION |
| WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science |
| WOS类目 | Chemistry, Physical ; Electrochemistry ; Energy & Fuels ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000401686100012 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2177412 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Lu, Shanfu; Xiang, Yan |
| 作者单位 | 1.Beihang Univ, Beijing Key Lab Bioinspired Energy Mat & Devices, Sch Space & Environm, Beijing 100191, Peoples R China 2.Beijing Inst Aeronaut Mat, Beijing 100095, Peoples R China 3.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Xin,Peng, Sikan,Lu, Shanfu,et al. Modulation of of the microstructure of the ag/c-based alkaline cathode via the ionomer content for a bipolar membrane fuel cell[J]. Journal of power sources,2017,354:92-99. |
| APA | Xu, Xin.,Peng, Sikan.,Lu, Shanfu.,Gong, Jian.,Zhang, Jin.,...&Xiang, Yan.(2017).Modulation of of the microstructure of the ag/c-based alkaline cathode via the ionomer content for a bipolar membrane fuel cell.Journal of power sources,354,92-99. |
| MLA | Xu, Xin,et al."Modulation of of the microstructure of the ag/c-based alkaline cathode via the ionomer content for a bipolar membrane fuel cell".Journal of power sources 354(2017):92-99. |
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