Electronic configuration and ligand nature of five-coordinate iron porphyrin carbene complexes: an experimental study
文献类型：期刊论文
| 作者 | Liu, Yulong1; Xu, Wei2; Zhang, Jing2; Fuller, William3; Schulz, Charles E.3; Li, Jianfeng1 |
| 刊名 | Journal of the american chemical society
 |
| 出版日期 | 2017-04-12 |
| 卷号 | 139期号:14页码:5023-5026 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/jacs.7b01722 |
| 通讯作者 | Li, jianfeng(jfli@ucas.ac.cn) |
| 英文摘要 | The five-coordinate iron porphyrin carbene complexes [fe(tpp) (ccl2)] (tpp = tetraphenylporphyrin), [fe(ttp) (ccl2)] (ttp = tetratolylporphyrin) and [fe(tfpp) (cph2)] (tfpp = tetra(pentafluoro-phenyl)porphyrin), utilizing two types of carbene ligands (ccl2 and cph2), have been investigated by single crystal x-ray, xanes (x-ray absorption near edge spectroscopy), mossbauer, nmr and uv-vis spectroscopies. the xanes suggested the iron(ii) oxidation state of the complexes. the multitemperature and high magnetic field mossbauer experiments, which show very large quadrupole splittings (qs, delta e-q), determined the s = 0 electronic configuration. more importantly, combined structural and mossbauer studies, especially the comparison with the low spin iron(ii) porphyrin complexes with strong diatomic ligands (cs, co and cn-) revealed the covalent bond nature of the carbene ligands. a correlation between the iron isomer shifts (is, delta) and the axial bond distances is established for the first time for these donor carbon ligands (:c-r). |
| WOS关键词 | METAL-ORGANIC FRAMEWORK ; PICKET-FENCE PORPHYRINS ; MOSSBAUER-SPECTROSCOPY ; MOLECULAR-STRUCTURE ; AXIAL LIGAND ; CYTOCHROME-P-450 ; HEMOPROTEINS ; CRYSTAL ; REACTIVITY ; OXIDATION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000399353800011 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2177464 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Li, Jianfeng |
| 作者单位 | 1.Univ Chinese Acad Sci, Coll Mat Sci & Optoelect Technol, Beijing 101408, Peoples R China 2.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China 3.Knox Coll, Dept Phys, Galesburg, IL 61401 USA |
| 推荐引用方式 GB/T 7714 | Liu, Yulong,Xu, Wei,Zhang, Jing,et al. Electronic configuration and ligand nature of five-coordinate iron porphyrin carbene complexes: an experimental study[J]. Journal of the american chemical society,2017,139(14):5023-5026. |
| APA | Liu, Yulong,Xu, Wei,Zhang, Jing,Fuller, William,Schulz, Charles E.,&Li, Jianfeng.(2017).Electronic configuration and ligand nature of five-coordinate iron porphyrin carbene complexes: an experimental study.Journal of the american chemical society,139(14),5023-5026. |
| MLA | Liu, Yulong,et al."Electronic configuration and ligand nature of five-coordinate iron porphyrin carbene complexes: an experimental study".Journal of the american chemical society 139.14(2017):5023-5026. |
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