One-step solid state synthesis of ptco nanocubes/graphene nanocomposites as advanced oxygen reduction reaction electrocatalysts
文献类型:期刊论文
作者 | He, Chunyong1,2; Zhang, Shengkai1,2; Tao, Juzhou1,2; Shen, Pei Kang3 |
刊名 | Journal of catalysis
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出版日期 | 2018-06-01 |
卷号 | 362页码:85-93 |
关键词 | Ptco nanocubes Graphene Core-shell structure Solid state synthesis Oxygen reduction reaction |
ISSN号 | 0021-9517 |
DOI | 10.1016/j.jcat.2018.03.025 |
通讯作者 | He, chunyong(hechunyong@ihep.ac.cn) ; Tao, juzhou(taoj@ihep.ac.cn) |
英文摘要 | Here, we report the synthesis of ptco nanocubes with core-shell structure on graphene surface by a novel solid state method. since no organic agent and surfactant was used during the synthesis process, the ptco nanocubes surface is definite clean. the mean grain size of ptco nanocubes is just about 5 nm, and ptco nanocubes possess core-shell structure with ptco core and a thin pt-rich shell (about 3-5 atomic layers) on the surface. compared with commercial pt/c catalyst, the ptco nanocubes exhibit an 8.4 times mass activity enhancement toward oxygen reduction reaction (orr). besides, the ptco nanocubes show extreme high electrochemical durability. (c) 2018 elsevier inc. all rights reserved. |
WOS关键词 | FUEL-CELL CATALYSTS ; CORE-SHELL NANOPARTICLES ; TRANSITION-METALS ; ALLOY CATALYSTS ; PLATINUM ; STABILITY ; CARBON ; TEMPERATURE ; MORPHOLOGY ; NANOWIRES |
WOS研究方向 | Chemistry ; Engineering |
WOS类目 | Chemistry, Physical ; Engineering, Chemical |
语种 | 英语 |
WOS记录号 | WOS:000432770900011 |
出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2177539 |
专题 | 高能物理研究所 |
通讯作者 | He, Chunyong; Tao, Juzhou |
作者单位 | 1.Dongguan Neutron Sci Ctr, Dongguan 523803, Peoples R China 2.Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China 3.Guangxi Univ, Collaborat Innovat Ctr Sustainable Energy Mat, Nanning 530009, Guangxi, Peoples R China |
推荐引用方式 GB/T 7714 | He, Chunyong,Zhang, Shengkai,Tao, Juzhou,et al. One-step solid state synthesis of ptco nanocubes/graphene nanocomposites as advanced oxygen reduction reaction electrocatalysts[J]. Journal of catalysis,2018,362:85-93. |
APA | He, Chunyong,Zhang, Shengkai,Tao, Juzhou,&Shen, Pei Kang.(2018).One-step solid state synthesis of ptco nanocubes/graphene nanocomposites as advanced oxygen reduction reaction electrocatalysts.Journal of catalysis,362,85-93. |
MLA | He, Chunyong,et al."One-step solid state synthesis of ptco nanocubes/graphene nanocomposites as advanced oxygen reduction reaction electrocatalysts".Journal of catalysis 362(2018):85-93. |
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来源:高能物理研究所
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