Novel viologen derivative based uranyl coordination polymers featuring photochromic behaviors
文献类型：期刊论文
| 作者 | Hu, Kong-Qiu1; Wu, Qun-Yan1; Mei, Lei1; Zhang, Xiao-Lin1; Ma, Lei1; Song, Gang2; Chen, Di-Yun2; Wang, Yi-Tong3; Chai, Zhi-Fang1; Shi, Wei-Qun1 |
| 刊名 | Chemistry-a european journal
 |
| 出版日期 | 2017-12-19 |
| 卷号 | 23期号:71页码:18074-18083 |
| ISSN号 | 0947-6539 |
| 关键词 | Coordination polymers Isomery Photochromic Uranyl Viologen derivative |
| DOI | 10.1002/chem.201704478 |
| 通讯作者 | Shi, wei-qun(shiwq@ihep.ac.cn) |
| 英文摘要 | A series of novel uranyl coordination polymers have been synthesized by hydrothermal reactions. both complexes 1 and 2 prosess two ipbp(-) ligands (h(2)ipbpcl=1-(3,5-dicarboxyphenyl)-4,4-bipyridinium chloride), one uranyl cation, and two coordination water molecules, which can further extend to 2d networks through hydrogen bonding. in complex 1, two sets of equivalent nets are entangled together, resulting in a 2d + 2d 3d polycatenated framework. in complex 2, the neighbouring equivalent nets interpenetrate each other, forming a twofold interpenetrated network. complexes 3 and 4 are isomers, and both of them are constructed from (uo2)(2)(oh)(2) dinuclear units, which are connected with four ipbp(-) ligands. the 3d structures of complexes 3 and 4 are similar along the b axis. similar to other viologen-based coordination polymers, complexes 3 and 4 exhibit photochromic and thermochromic properties, which are rarely observed in actinide coordination polymers. unlike the monotonous coordination mode in complexes 1-4, the ipbp(-) ligands feature a (3)-bridge through two kinds of coordination modes in complex 5. notably, complex 5 presents a unique example in which terminal pyridine nitrogen atom is involved in the coordination. |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; CATION-CATION INTERACTIONS ; BASIS-SETS ; CRYSTAL-STRUCTURES ; TRANSITION-METAL ; 3D FRAMEWORK ; 1D CHAIN ; URANIUM ; COMPLEXES ; LUMINESCENCE |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000418356700032 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2177844 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Shi, Wei-Qun |
| 作者单位 | 1.Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China 2.Guangzhou Univ, Sch Environm Sci & Engn, Guangdong Prov Key Lab Radionuclide Pollut Contro, Guangzhou 510006, Guangdong, Peoples R China 3.China Int Engn Consulting Corp, Beijing 100089, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Kong-Qiu,Wu, Qun-Yan,Mei, Lei,et al. Novel viologen derivative based uranyl coordination polymers featuring photochromic behaviors[J]. Chemistry-a european journal,2017,23(71):18074-18083. |
| APA | Hu, Kong-Qiu.,Wu, Qun-Yan.,Mei, Lei.,Zhang, Xiao-Lin.,Ma, Lei.,...&Shi, Wei-Qun.(2017).Novel viologen derivative based uranyl coordination polymers featuring photochromic behaviors.Chemistry-a european journal,23(71),18074-18083. |
| MLA | Hu, Kong-Qiu,et al."Novel viologen derivative based uranyl coordination polymers featuring photochromic behaviors".Chemistry-a european journal 23.71(2017):18074-18083. |
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来源：高能物理研究所
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