Visible light induced trifluoromethyl migration: easy access to alpha-trifluoromethylated ketones from enol triflates
文献类型：期刊论文
| 作者 | Liu, Shuyang1; Jie, Jiyang1; Yu, Jipan2,3; Yang, Xiaobo1 |
| 刊名 | Advanced synthesis & catalysis
 |
| 出版日期 | 2018-01-17 |
| 卷号 | 360期号:2页码:267-271 |
| 关键词 | Visible light induced Radical Migration Trifluoromethylation Enol triflate |
| ISSN号 | 1615-4150 |
| DOI | 10.1002/adsc.201701051 |
| 通讯作者 | Yang, xiaobo(bxy1223@gmail.com) |
| 英文摘要 | Herein, we reported a novel method to synthesize alpha-trifluoromethylated ketones from enol triflates. involving a cascade sulfur dioxide extrusion and a cf3 (trifluoromethyl) radical addition process, this reaction proceeds at room temperature and is driven by visible light irradiation. this protocol bears good functional group compatibility, which can generate the desired products in good to excellent yields even in gram scale. it is hoped that this approach to generate cf3 radicals from enol triflates can be used in other radical-involved reactions. |
| WOS关键词 | RADICAL TRIFLUOROMETHYLATION ; ELECTROPHILIC TRIFLUOROMETHYLATION ; PHOTOREDOX CATALYSIS ; ROOM-TEMPERATURE ; OXIDATIVE TRIFLUOROMETHYLATION ; MEDIATED TRIFLUOROMETHYLATION ; CARBONYL-COMPOUNDS ; FUNCTIONAL-GROUPS ; HIGHLY EFFICIENT ; LANGLOIS REAGENT |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Applied ; Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000422659800009 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2177870 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Yang, Xiaobo |
| 作者单位 | 1.Shenyang Normal Univ, Inst Catalysis Energy & Environm, Coll Chem & Chem Engn, Shenyang 110034, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst High Energy Phys, Key Lab Nucl Radiat & Nucl Energy Technol, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Inst High Energy Phys, Key Lab Biomed Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Shuyang,Jie, Jiyang,Yu, Jipan,et al. Visible light induced trifluoromethyl migration: easy access to alpha-trifluoromethylated ketones from enol triflates[J]. Advanced synthesis & catalysis,2018,360(2):267-271. |
| APA | Liu, Shuyang,Jie, Jiyang,Yu, Jipan,&Yang, Xiaobo.(2018).Visible light induced trifluoromethyl migration: easy access to alpha-trifluoromethylated ketones from enol triflates.Advanced synthesis & catalysis,360(2),267-271. |
| MLA | Liu, Shuyang,et al."Visible light induced trifluoromethyl migration: easy access to alpha-trifluoromethylated ketones from enol triflates".Advanced synthesis & catalysis 360.2(2018):267-271. |
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来源：高能物理研究所
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