Elevated performance of hybrid membranes by incorporating metal organic framework cubtc for pervaporative desulfurization of gasoline
文献类型:期刊论文
作者 | Yu, Shengnan1,2; Jiang, Zhongyi1,2; Li, Weidong1,2; Mayta, Josue Quispe1,2; Ding, He1,2; Song, Yimeng1,2; Li, Zhe1,2; Dong, Zhiwei2,3; Pan, Fusheng1,2,5; Wang, Baoyi4 |
刊名 | Chemical engineering and processing
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出版日期 | 2018 |
卷号 | 123页码:12-19 |
关键词 | Hybrid membrane Polyether-block-amide Metal organic framework Pervaporation Desulfurization |
ISSN号 | 0255-2701 |
DOI | 10.1016/j.cep.2017.11.001 |
通讯作者 | Pan, fusheng(fspan@tju.edu.cn) |
英文摘要 | Metal organic framework cubtc nanoparticles were incorporated into polyether-block-amide (pebax) to promote the transport of penetrant molecules in the membranes. the cubtc nanoparticles can form hydrogen bonds with the pebax chains, thus interfered with the chain packing and tailored the free volume properties of pebax. the channels and active metal sites of cubtc promoted the transport of sulfur-containing molecules when the membranes were employed for gasoline desulfurization. when the filler content was 2 wt%, the optimal separation performance was achieved with a permeation flux of 4.4 kg/(m(2) h) and a thiophene enrichment factor of 6.0 at 40 degrees c, increased by 36% and 11% compared with the pebax pristine membrane. the comprehensive performance of the membranes is more competitive than widely-used pdms membranes, especially under high temperatures. a permeation flux of 16.45 kg/(m(2) h) is reached with an enrichment factor of 4.04 at 70 degrees c. |
WOS关键词 | MIXED MATRIX MEMBRANES ; COMPOSITE MEMBRANE ; INTERFACIAL STABILITY ; MODEL GASOLINE ; SEPARATION |
WOS研究方向 | Energy & Fuels ; Engineering |
WOS类目 | Energy & Fuels ; Engineering, Chemical |
语种 | 英语 |
WOS记录号 | WOS:000424180200002 |
出版者 | ELSEVIER SCIENCE SA |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2178006 |
专题 | 高能物理研究所 |
通讯作者 | Pan, Fusheng |
作者单位 | 1.Tianjin Univ, Sch Chem Engn & Technol, Minist Educ, Key Lab Green Chem Technol, Tianjin 300354, Peoples R China 2.Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China 3.Nankai Univ, Coll Chem, Tianjin 300071, Peoples R China 4.Chinese Acad Sci, Inst High Energy Phys, Multidiscipline Res Div, Beijing 100049, Peoples R China 5.Tianjin Polytech Univ, State Key Lab Separat Membranes & Membrane Proc, Tianjin 300387, Peoples R China |
推荐引用方式 GB/T 7714 | Yu, Shengnan,Jiang, Zhongyi,Li, Weidong,et al. Elevated performance of hybrid membranes by incorporating metal organic framework cubtc for pervaporative desulfurization of gasoline[J]. Chemical engineering and processing,2018,123:12-19. |
APA | Yu, Shengnan.,Jiang, Zhongyi.,Li, Weidong.,Mayta, Josue Quispe.,Ding, He.,...&Cao, Xingzhong.(2018).Elevated performance of hybrid membranes by incorporating metal organic framework cubtc for pervaporative desulfurization of gasoline.Chemical engineering and processing,123,12-19. |
MLA | Yu, Shengnan,et al."Elevated performance of hybrid membranes by incorporating metal organic framework cubtc for pervaporative desulfurization of gasoline".Chemical engineering and processing 123(2018):12-19. |
入库方式: iSwitch采集
来源:高能物理研究所
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