中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Elevated performance of hybrid membranes by incorporating metal organic framework cubtc for pervaporative desulfurization of gasoline

文献类型:期刊论文

作者Yu, Shengnan1,2; Jiang, Zhongyi1,2; Li, Weidong1,2; Mayta, Josue Quispe1,2; Ding, He1,2; Song, Yimeng1,2; Li, Zhe1,2; Dong, Zhiwei2,3; Pan, Fusheng1,2,5; Wang, Baoyi4
刊名Chemical engineering and processing
出版日期2018
卷号123页码:12-19
关键词Hybrid membrane Polyether-block-amide Metal organic framework Pervaporation Desulfurization
ISSN号0255-2701
DOI10.1016/j.cep.2017.11.001
通讯作者Pan, fusheng(fspan@tju.edu.cn)
英文摘要Metal organic framework cubtc nanoparticles were incorporated into polyether-block-amide (pebax) to promote the transport of penetrant molecules in the membranes. the cubtc nanoparticles can form hydrogen bonds with the pebax chains, thus interfered with the chain packing and tailored the free volume properties of pebax. the channels and active metal sites of cubtc promoted the transport of sulfur-containing molecules when the membranes were employed for gasoline desulfurization. when the filler content was 2 wt%, the optimal separation performance was achieved with a permeation flux of 4.4 kg/(m(2) h) and a thiophene enrichment factor of 6.0 at 40 degrees c, increased by 36% and 11% compared with the pebax pristine membrane. the comprehensive performance of the membranes is more competitive than widely-used pdms membranes, especially under high temperatures. a permeation flux of 16.45 kg/(m(2) h) is reached with an enrichment factor of 4.04 at 70 degrees c.
WOS关键词MIXED MATRIX MEMBRANES ; COMPOSITE MEMBRANE ; INTERFACIAL STABILITY ; MODEL GASOLINE ; SEPARATION
WOS研究方向Energy & Fuels ; Engineering
WOS类目Energy & Fuels ; Engineering, Chemical
语种英语
WOS记录号WOS:000424180200002
出版者ELSEVIER SCIENCE SA
URI标识http://www.irgrid.ac.cn/handle/1471x/2178006
专题高能物理研究所
通讯作者Pan, Fusheng
作者单位1.Tianjin Univ, Sch Chem Engn & Technol, Minist Educ, Key Lab Green Chem Technol, Tianjin 300354, Peoples R China
2.Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China
3.Nankai Univ, Coll Chem, Tianjin 300071, Peoples R China
4.Chinese Acad Sci, Inst High Energy Phys, Multidiscipline Res Div, Beijing 100049, Peoples R China
5.Tianjin Polytech Univ, State Key Lab Separat Membranes & Membrane Proc, Tianjin 300387, Peoples R China
推荐引用方式
GB/T 7714
Yu, Shengnan,Jiang, Zhongyi,Li, Weidong,et al. Elevated performance of hybrid membranes by incorporating metal organic framework cubtc for pervaporative desulfurization of gasoline[J]. Chemical engineering and processing,2018,123:12-19.
APA Yu, Shengnan.,Jiang, Zhongyi.,Li, Weidong.,Mayta, Josue Quispe.,Ding, He.,...&Cao, Xingzhong.(2018).Elevated performance of hybrid membranes by incorporating metal organic framework cubtc for pervaporative desulfurization of gasoline.Chemical engineering and processing,123,12-19.
MLA Yu, Shengnan,et al."Elevated performance of hybrid membranes by incorporating metal organic framework cubtc for pervaporative desulfurization of gasoline".Chemical engineering and processing 123(2018):12-19.

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来源:高能物理研究所

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