Study on structure and property relations of -ipp during uniaxial deformation via in situ synchrotron saxs/waxs and pom investigations
文献类型:期刊论文
作者 | Shang, Yingrui1; Ning, Puqing1; Zhang, Yao1; Xue, Feifei1; Cai, Ziwei1; Li, Jingqing1; Ma, Guiqiu1; Song, Jian2; Wu, Zhonghua3; Jiang, Shichun1 |
刊名 | Polymer engineering and science
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出版日期 | 2018-02-01 |
卷号 | 58期号:2页码:160-169 |
ISSN号 | 0032-3888 |
DOI | 10.1002/pen.24543 |
通讯作者 | Shang, yingrui(yingrui.shang@gmail.com) ; Jiang, shichun(scjiang@tju.edu.cn) |
英文摘要 | Micro- and meso-scale structure changes of -form isotactic polypropylene (-ipp) during uniaxial stretching is studied by time-resolved synchrotron small-angle x-ray scattering (saxs) and wide-angle x-ray scattering (waxs). the structure/property relations are investigated at different temperatures, and the effects of isothermal crystallization are also studied with pom. the x-ray scattering results show that the long period increased and the lamellar oriented along the stretching direction in the elastic deformation stage. the lamellar and crystals start destructing after yielding. and from it pom images it can be seen that with higher crystallization temperature the spherulites connected to form a crystalline network, on which the stress is mainly loaded. it turns out different environment temperatures affect mostly the amorphous domains. and samples exhibit different yielding mechanisms with different thermal histories. a hypothetical structural mechanism is proposed based to explain the observed relationship between the processing parameters, thermal history and the structure/property relations of -ipp. polym. eng. sci., 58:160-169, 2018. (c) 2017 society of plastics engineers |
WOS关键词 | ISOTACTIC POLYPROPYLENE FILMS ; ETHYLENE-PROPYLENE COPOLYMER ; X-RAY-SCATTERING ; MECHANICAL-PROPERTIES ; SEMICRYSTALLINE POLYMERS ; CRYSTALLINE POLYMERS ; TENSILE DEFORMATION ; PLASTIC-DEFORMATION ; ROOM-TEMPERATURE ; CRITICAL STRAINS |
WOS研究方向 | Engineering ; Polymer Science |
WOS类目 | Engineering, Chemical ; Polymer Science |
语种 | 英语 |
WOS记录号 | WOS:000424843000005 |
出版者 | WILEY |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2178053 |
专题 | 高能物理研究所 |
通讯作者 | Shang, Yingrui; Jiang, Shichun |
作者单位 | 1.Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China 2.Tianjin Univ, Sch Chem Engn, Tianjin 300072, Peoples R China 3.Chinese Acad Sci, Beijing Synchrotron Radiat Lab, Inst High Energy Phys, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Shang, Yingrui,Ning, Puqing,Zhang, Yao,et al. Study on structure and property relations of -ipp during uniaxial deformation via in situ synchrotron saxs/waxs and pom investigations[J]. Polymer engineering and science,2018,58(2):160-169. |
APA | Shang, Yingrui.,Ning, Puqing.,Zhang, Yao.,Xue, Feifei.,Cai, Ziwei.,...&Jiang, Shichun.(2018).Study on structure and property relations of -ipp during uniaxial deformation via in situ synchrotron saxs/waxs and pom investigations.Polymer engineering and science,58(2),160-169. |
MLA | Shang, Yingrui,et al."Study on structure and property relations of -ipp during uniaxial deformation via in situ synchrotron saxs/waxs and pom investigations".Polymer engineering and science 58.2(2018):160-169. |
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来源:高能物理研究所
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