Design of single-atom co-n-5 catalytic site: a robust electrocatalyst for co2 reduction with nearly 100% co selectivity and remarkable stability
文献类型：期刊论文
| 作者 | Pan, Yuan1; Lin, Rui1; Chen, Yinjuan1,2; Liu, Shoujie1,3; Zhu, Wei1; Cao, Xing1; Chen, Wenxing1; Wu, Konglin1,3; Cheong, Weng-Chon1; Wang, Yu1 |
| 刊名 | Journal of the american chemical society
 |
| 出版日期 | 2018-03-28 |
| 卷号 | 140期号:12页码:4218-4221 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/jacs.8b00814 |
| 通讯作者 | Chen, chen(cchen@mail.tsinghua.edu.cn) |
| 英文摘要 | We develop an n-coordination strategy to design a robust co2 reduction reaction (co2rr) electrocatalyst with atomically dispersed co-n-5 site anchored on polymer-derived hollow n-doped porous carbon spheres. our catalyst exhibits high selectivity for co2rr with co faradaic efficiency (feco) above 90% over a wide potential range from -0.57 to -0.88 v (the feco exceeded 99% at -0.73 and -0.79 v). the co current density and feco remained nearly unchanged after electrolyzing 10 h, revealing remarkable stability. experiments and density functional theory calculations demonstrate single-atom co-n-5 site is the dominating active center simultaneously for co2 activation, the rapid formation of key intermediate cooh* as well as the desorption of co. |
| WOS关键词 | ELECTROCHEMICAL REDUCTION ; CARBON-DIOXIDE ; ELECTROREDUCTION ; PHOTOSYNTHESIS ; ELECTRODES ; EVOLUTION ; METALS ; WATER |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000428972200008 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2178164 |
| 专题 | 高能物理研究所 |
| 通讯作者 | Chen, Chen |
| 作者单位 | 1.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China 2.China Univ Petr East China, State Key Lab Heavy Oil Proc, Qingdao 266580, Peoples R China 3.Anhui Normal Univ, Coll Chem & Mat Sci, Wuhu 241000, Peoples R China 4.Chinese Acad Sci, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China 5.Tianjin Univ Technol, Ctr Electron Microscopy, Tianjin 300384, Peoples R China 6.Tsinghua Univ, Dept Chem Engn, Beijing 100084, Peoples R China 7.Univ Sci & Technol Beijing, Dept Chem, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pan, Yuan,Lin, Rui,Chen, Yinjuan,et al. Design of single-atom co-n-5 catalytic site: a robust electrocatalyst for co2 reduction with nearly 100% co selectivity and remarkable stability[J]. Journal of the american chemical society,2018,140(12):4218-4221. |
| APA | Pan, Yuan.,Lin, Rui.,Chen, Yinjuan.,Liu, Shoujie.,Zhu, Wei.,...&Li, Yadong.(2018).Design of single-atom co-n-5 catalytic site: a robust electrocatalyst for co2 reduction with nearly 100% co selectivity and remarkable stability.Journal of the american chemical society,140(12),4218-4221. |
| MLA | Pan, Yuan,et al."Design of single-atom co-n-5 catalytic site: a robust electrocatalyst for co2 reduction with nearly 100% co selectivity and remarkable stability".Journal of the american chemical society 140.12(2018):4218-4221. |
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