Effect of confinement of TiO2 nanotubes over the Ru nanoparticles on Fischer-Tropsch synthesis
文献类型：期刊论文
| 作者 | Yang, Xu1; Wang, Wenbo1; Wu, Liangpeng1; Li, Xinjun1; Wang, Tiejun1; Liao, Shijun2 |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 2016-09-25 |
| 卷号 | 526页码:45-52 |
| 关键词 | Confinement Tio2 Nanotubes Ruthenium Fischer-tropsch Synthesis |
| DOI | 10.1016/j.apcata.2016.07.021 |
| 文献子类 | Article |
| 英文摘要 | Ru nanoparticles (NPs) have been successfully deposited in the inner pores of TiO2 nanotubes (TNTs), denoted as Ru-in/TNT, by vacuum assisted impregnation method for Fischer-Tropsch synthesis (FTS). The composition, morphology and electronic properties have been characterized by the XRD, TEM, N-2-sorption, H-2-TPR/TPD and XPS, investigating the confinement effect of TNT on the entrapped Ru NPs' FTS performance. The Ru-in/TNT exhibits high CO conversion activity and superior deactivation-resist ability over the Ru-out/TNT (with most of Ru NPs deposited on the outer surface of TNT) and Ru/P25 (using commercial P25 powder as support) catalysts. Besides above superiority, the Ru-in/TNT facilitates the formation of long chain (C19+) products as well. The enhanced activity and selectivity can be ascribed to the confinement effect of TNT: (i) strengthen charge transfer and modulate the electronic properties of Ru species resulting in more active center site; (ii) constrain the metal sintering and metal leaching to resist deactivation during FTS; (iii) facilitate the re-adsorption of ce-olefin leading to long-chain product. (C) 2016 Elsevier B.V. All rights reserved. |
| WOS关键词 | CARBON NANOTUBES ; RUTHENIUM NANOPARTICLES ; TITANATE NANOTUBES ; REACTION PATHWAY ; SYNTHESIS GAS ; CATALYSTS ; DEACTIVATION ; SUPPORT ; SIZE ; HYDROGENATION |
| 语种 | 英语 |
| WOS记录号 | WOS:000384865600006 |
| 资助机构 | National Scientific Foundation of China(21303210) ; National 973 Project of China(2013CB228105) |
| 源URL | [http://ir.giec.ac.cn/handle/344007/13951]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Xu,Wang, Wenbo,Wu, Liangpeng,et al. Effect of confinement of TiO2 nanotubes over the Ru nanoparticles on Fischer-Tropsch synthesis[J]. APPLIED CATALYSIS A-GENERAL,2016,526:45-52. |
| APA | Yang, Xu,Wang, Wenbo,Wu, Liangpeng,Li, Xinjun,Wang, Tiejun,&Liao, Shijun.(2016).Effect of confinement of TiO2 nanotubes over the Ru nanoparticles on Fischer-Tropsch synthesis.APPLIED CATALYSIS A-GENERAL,526,45-52. |
| MLA | Yang, Xu,et al."Effect of confinement of TiO2 nanotubes over the Ru nanoparticles on Fischer-Tropsch synthesis".APPLIED CATALYSIS A-GENERAL 526(2016):45-52. |
入库方式： OAI收割
来源：广州能源研究所
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