Development of low-temperature desulfurization performance of a MnO2/AC composite for a combined SO2 trap for diesel exhaust
文献类型：期刊论文
| 作者 | Liu, X. C.1,2; Osaka, Y.3; Huang, H. Y.1; Huhetaoli1; Li, J.4 ; Yang, X. X.1; Li, S. J.1,2; Kobayashi, N.4
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| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:98页码:96367-96375 |
| DOI | 10.1039/c6ra19017k |
| 文献子类 | Article |
| 英文摘要 | Growing concern about the removal of sulfur dioxide (SO2) from combustion exhaust has resulted in the development of desulfurization materials for a SO2 trap. In this study, a manganese dioxide/activated carbon (MnO2/AC) composite was proposed as a low temperature desulfurization material for a combined SO2 trap. The MnO2/AC composite was synthesized using a redox deposition method and characterized using scanning electron microscopy (SEM), nitrogen adsorption, X-ray fluorescence spectrometry (XRF) and Fourier transform infrared (FTIR) spectroscopy. The SO2 adsorption capacity of the composites was measured using thermogravimetry and the SO2 adsorption characteristics were also investigated. In the low temperature region (50-200 degrees C), the MnO2/AC composite exhibits good SO2 trap performance and the MnO2 conversion of the composite is significantly improved. It was found that the SO2 adsorption on the MnO2/AC composite is a chemisorption process. The experimental data for SO2 adsorption on the MnO2/AC composite could fit the Freundlich model well. Changes in the thermodynamic parameters were determined. The calculated values of Delta G(0) and Delta H-0 indicate that the SO2 adsorption on the MnO2/AC composite is spontaneous and thermodynamically favorable. |
| WOS关键词 | ACTIVATED CARBON ; SIMULTANEOUS REMOVAL ; SULFUR-DIOXIDE ; ADSORPTION ; OXIDATION ; REGENERATION ; CATALYSTS ; SORPTION ; FILTER ; FRESH |
| 语种 | 英语 |
| WOS记录号 | WOS:000385633100119 |
| 资助机构 | National Natural Science Foundation of China (NSFC) through International (Regional) Cooperation and Exchange Projects(21550110494) |
| 源URL | [http://ir.giec.ac.cn/handle/344007/13973]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, 2 Nengyuan Rd Wushan, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Kanazawa Univ, Kanazawa, Ishikawa 9201192, Japan 4.Nagoya Univ, Chikusa Ku, Furo Cho, Nagoya, Aichi 4648603, Japan |
| 推荐引用方式 GB/T 7714 | Liu, X. C.,Osaka, Y.,Huang, H. Y.,et al. Development of low-temperature desulfurization performance of a MnO2/AC composite for a combined SO2 trap for diesel exhaust[J]. RSC ADVANCES,2016,6(98):96367-96375. |
| APA | Liu, X. C..,Osaka, Y..,Huang, H. Y..,Huhetaoli.,Li, J..,...&Kobayashi, N..(2016).Development of low-temperature desulfurization performance of a MnO2/AC composite for a combined SO2 trap for diesel exhaust.RSC ADVANCES,6(98),96367-96375. |
| MLA | Liu, X. C.,et al."Development of low-temperature desulfurization performance of a MnO2/AC composite for a combined SO2 trap for diesel exhaust".RSC ADVANCES 6.98(2016):96367-96375. |
入库方式： OAI收割
来源：广州能源研究所
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