Hydrodeoxygenation of Anisole over Ni/alpha-Al2O3 Catalyst
文献类型:期刊论文
| 作者 | Tang, Wen-wu1,3; Zhang, Xing-hua2,3 ; Zhang, Qi2,3 ; Wang, Tie-jun2,3 ; Ma, Long-long2,3
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| 刊名 | CHINESE JOURNAL OF CHEMICAL PHYSICS
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| 出版日期 | 2016-10-01 |
| 卷号 | 29期号:5页码:617-622 |
| 关键词 | Anisole Hydrodeoxygenation Ni/alpha-al2o3 Hydrocarbons |
| DOI | 10.1063/1674-0068/29/cjcp1603062 |
| 文献子类 | Article |
| 英文摘要 | Ni-based catalysts supported on different supports (alpha-Al2O3, gamma-Al2O3, SiO2, TiO2, and ZrO2) were prepared by impregnation. Effects of supports on catalytic performance were tested using hydrodeoxygenation reaction (HDO) of anisole as model reaction. Ni/alpha-Al2O3 was found to be the highest active catalyst for HDO of anisole. Under the optimal conditions, the anisole conversion is 93.25% and the hydrocarbon yield is 90.47%. Catalyst characterization using H-2-TPD method demonstrates that Ni/alpha-Al2O3 catalyst possesses more amount of active metal Ni than those of other investigated catalysts, which can enhance the catalytic activity for hydrogenation. Furthermore, it is found that the Ni/alpha-Al2O3 catalyst has excellent repeatability, and the carbon deposited on the surface of catalyst is negligible. |
| WOS关键词 | LIGNIN DEPOLYMERIZATION ; PHENOLIC-COMPOUNDS ; AQUEOUS-PHASE ; BIO-OIL ; EFFICIENT ; GUAIACOL ; DECOMPOSITION ; HYDROCARBONS ; VALORIZATION ; CONVERSION |
| 语种 | 英语 |
| WOS记录号 | WOS:000388063400015 |
| 资助机构 | National Natural Science Foundation of China(51576198) ; National Key Technology RD Program(2014BAD02B01) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015288) |
| 源URL | [http://ir.giec.ac.cn/handle/344007/13975] ![]() |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Wen-wu,Zhang, Xing-hua,Zhang, Qi,et al. Hydrodeoxygenation of Anisole over Ni/alpha-Al2O3 Catalyst[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2016,29(5):617-622. |
| APA | Tang, Wen-wu,Zhang, Xing-hua,Zhang, Qi,Wang, Tie-jun,&Ma, Long-long.(2016).Hydrodeoxygenation of Anisole over Ni/alpha-Al2O3 Catalyst.CHINESE JOURNAL OF CHEMICAL PHYSICS,29(5),617-622. |
| MLA | Tang, Wen-wu,et al."Hydrodeoxygenation of Anisole over Ni/alpha-Al2O3 Catalyst".CHINESE JOURNAL OF CHEMICAL PHYSICS 29.5(2016):617-622. |
入库方式: OAI收割
来源:广州能源研究所
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