中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effect of Ru Particle Size on Hydrogenation/Decarbonylation of Propanoic Acid Over Supported Ru Catalysts in Aqueous Phase

文献类型:期刊论文

作者Chen, Lungang; Li, Yuping; Zhang, Xinghua; Zhang, Qi; Wang, Tiejun; Ma, Longlong
刊名CATALYSIS LETTERS
出版日期2017
卷号147期号:1页码:29-38
关键词Ru Loading Carboxylic Acid Hydrogenation Decarbonylation C-c Cleavage
DOI10.1007/s10562-016-1877-4
文献子类Article
英文摘要The aqueous-phase hydrogenation of propanoic acid was performed over the Ru/ZrO2 and Ru/Al2O3 catalysts with different Ru loading. Combined with multiple characterization techniques, such as H-2-TPR, XRD, CO-FTIR, and DRIFTS of propanoic acid, the effect of Ru loading on the decarbonylation/hydrogenation of propanoic acid was investigated. Although hydrogenation/decarbonylation of carboxylic acids were strongly affected by the nature of supports, the increase of metal loading can cause the larger Ru particles and more bare Ru metal sites, which can facilitate the C-C bond cleavage reaction derived from the decarbonylation of propanoyl species over Ru metal sites.
WOS关键词ACETIC-ACID ; CO ADSORPTION ; LACTIC-ACID ; RUTHENIUM CATALYSTS ; SUCCINIC ACID ; HYDROGENATION ; BIOMASS ; HYDROGENOLYSIS ; REDUCTION ; CHEMICALS
语种英语
WOS记录号WOS:000394139200004
资助机构National Natural Science Foundation of China(51306189) ; Science and Technology Program of Guangdong Province(2014A010106022) ; Comprehensive Strategic Cooperation Project of Guangdong Province ; Chinese Academy of Sciences(2012B090400042) ; China-EU SMEs Cooperation Fund for Energy Conservation Research Project(SQ2013ZOB000002)
源URL[http://ir.giec.ac.cn/handle/344007/14047]  
专题中国科学院广州能源研究所
作者单位Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式
GB/T 7714
Chen, Lungang,Li, Yuping,Zhang, Xinghua,et al. Effect of Ru Particle Size on Hydrogenation/Decarbonylation of Propanoic Acid Over Supported Ru Catalysts in Aqueous Phase[J]. CATALYSIS LETTERS,2017,147(1):29-38.
APA Chen, Lungang,Li, Yuping,Zhang, Xinghua,Zhang, Qi,Wang, Tiejun,&Ma, Longlong.(2017).Effect of Ru Particle Size on Hydrogenation/Decarbonylation of Propanoic Acid Over Supported Ru Catalysts in Aqueous Phase.CATALYSIS LETTERS,147(1),29-38.
MLA Chen, Lungang,et al."Effect of Ru Particle Size on Hydrogenation/Decarbonylation of Propanoic Acid Over Supported Ru Catalysts in Aqueous Phase".CATALYSIS LETTERS 147.1(2017):29-38.

入库方式: OAI收割

来源:广州能源研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。