中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Study on process production of furfural and other chemicals from sugarcane bagasse in the phosphoric acid-tetrahydrofuran system

文献类型:期刊论文

作者Wang, Qiong1,2,3; Zhuang, Xinshu1,2,3; Qi, Wei1,2,3; Tan, Xuesong1,2,3; Yu, Qiang1,2,3; Yuan, Zhenhong1,2,3
刊名INTERNATIONAL JOURNAL OF OIL GAS AND COAL TECHNOLOGY
出版日期2017
卷号14期号:1-2页码:77-90
关键词Furfural Phosphoric Acid Tetrahydrofuran Thf Sugarcane Bagasse Cellulose
文献子类Article
英文摘要Cellulose degradation is inevitable during the production of furfural from biomass under the acidic systems; meanwhile, the simultaneous high yields of furfural and cellulose degradation product (5-HMF or levulinic acid) are hard to be achieved. To solve the problem and avoid the waste of cellulose, a method of producing furfural and preserving cellulosic residue was explored. Sugarcane bagasse was firstly pre-treated by phosphoric acid to obtain soluble xylo-oligosaccharides. And compared to the low furfural yields in phosphoric acid-water system based on response surface analysis, high furfural yields were obtained in the phosphoric acid-tetrahydrofuran (THF) system, meanwhile only trace cellulose was degraded. Furthermore, by a two-step rising temperature method, furfural yield reached to 66.59 mol%, and cellulose was depolymerised into glucooligosaccharides. After recovery of furfural, this research also investigated the conversion of glucooligosaccharides catalysed by the residual phosphoric acid, and it was found levulinic acid and extremely high yields of formic acid generated at 200 degrees C.
WOS关键词LIGNOCELLULOSE FRACTIONATION ; ENZYMATIC-HYDROLYSIS ; HYDROCHLORIC-ACID ; CELLULOSE ; CONVERSION ; BIOMASS ; HEMICELLULOSE ; XYLOSE ; YIELDS
语种英语
WOS记录号WOS:000397291200005
资助机构Natural Science Foundation of China(51506207 ; National Basic Research Program of China(2012CB215304) ; Youth Innovation Promotion Association, CAS(2015289) ; 21376241 ; 51561145015)
源URL[http://ir.giec.ac.cn/handle/344007/14065]  
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Beijing 100039, Peoples R China
3.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan, Peoples R China
推荐引用方式
GB/T 7714
Wang, Qiong,Zhuang, Xinshu,Qi, Wei,et al. Study on process production of furfural and other chemicals from sugarcane bagasse in the phosphoric acid-tetrahydrofuran system[J]. INTERNATIONAL JOURNAL OF OIL GAS AND COAL TECHNOLOGY,2017,14(1-2):77-90.
APA Wang, Qiong,Zhuang, Xinshu,Qi, Wei,Tan, Xuesong,Yu, Qiang,&Yuan, Zhenhong.(2017).Study on process production of furfural and other chemicals from sugarcane bagasse in the phosphoric acid-tetrahydrofuran system.INTERNATIONAL JOURNAL OF OIL GAS AND COAL TECHNOLOGY,14(1-2),77-90.
MLA Wang, Qiong,et al."Study on process production of furfural and other chemicals from sugarcane bagasse in the phosphoric acid-tetrahydrofuran system".INTERNATIONAL JOURNAL OF OIL GAS AND COAL TECHNOLOGY 14.1-2(2017):77-90.

入库方式: OAI收割

来源:广州能源研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。