Conversion of Cellulose to 5-Hydroxymethylfurfural using Inorganic Acidic Catalysts in the Presence of Pressurized Water Steam
文献类型：期刊论文
| 作者 | Cai, Chiliu1,2,3,4 ; Liu, Qiying1,2,3; Tan, Jin1,2,3; Wang, Tiejun1,2,3; Zhang, Qi1,2,3; Ma, Longlong1,2,3
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| 刊名 | BIORESOURCES
 |
| 出版日期 | 2017 |
| 卷号 | 12期号:1页码:1201-1215 |
| 关键词 | Cellulose Hmf Conversion Steam Stripping Process Fixed Bed |
| DOI | 10.15376/biores.12.1.1201-1215 |
| 文献子类 | Article |
| 英文摘要 | Traditionally, 5-hydroxymethylfurfural ( HMF) is produced by using a water-organic solvent medium, which inevitably increases production costs and adds subsequent separation processes. To minimize cost and/or toxic organic solvent usage, this study presents an effective pathway for producing HMF from cellulose. The process uses a fixed bed reactor with a steam stripping process in which the cellulose is converted into HMF and other products in the presence of acidic inorganic salts. In the process, the cellulose was hydrolyzed to glucose, which was followed by isomerization to fructose and fructose dehydration into HMF. The produced HMF was easily vaporized into the gas phase, which avoided its conversion into undesired byproducts. An acceptable HMF yield of 28.2 mol% was obtained using KH2PO4 as the catalyst at 270 degrees C. This technology could be used to obtain both HMF and furfural ( FF) from different lignocellulosic biomasses. This stripping technology has advantages such as the lack of organic solvents, showing an alternative and green HMF and/or FF production from lignocellulosic biomass. |
| WOS关键词 | LIQUID-WATER ; LEVULINIC ACID ; BIOMASS ; HYDROCARBONS ; HYDROLYSIS ; PRETREATMENT ; DEHYDRATION ; MECHANISM ; SOLVENTS ; ZEOLITE |
| 语种 | 英语 |
| WOS记录号 | WOS:000397065200088 |
| 资助机构 | National Science Foundation of China(51536009 ; 51576199 ; 51376185) |
| 源URL | [http://ir.giec.ac.cn/handle/344007/14076]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cai, Chiliu,Liu, Qiying,Tan, Jin,et al. Conversion of Cellulose to 5-Hydroxymethylfurfural using Inorganic Acidic Catalysts in the Presence of Pressurized Water Steam[J]. BIORESOURCES,2017,12(1):1201-1215. |
| APA | Cai, Chiliu,Liu, Qiying,Tan, Jin,Wang, Tiejun,Zhang, Qi,&Ma, Longlong.(2017).Conversion of Cellulose to 5-Hydroxymethylfurfural using Inorganic Acidic Catalysts in the Presence of Pressurized Water Steam.BIORESOURCES,12(1),1201-1215. |
| MLA | Cai, Chiliu,et al."Conversion of Cellulose to 5-Hydroxymethylfurfural using Inorganic Acidic Catalysts in the Presence of Pressurized Water Steam".BIORESOURCES 12.1(2017):1201-1215. |
入库方式： OAI收割
来源：广州能源研究所
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