Synthesis of Glycerol Carbonate from Glycerol and Dimethyl Carbonate Using Ionic Liquid Catalysts
文献类型：期刊论文
| 作者 | Miao, Changlin1,2,3; Fan, Pei1,2,3,4; Zhuang, Xinshu1,2,3 ; Wang, Zhongming1,2,3; Li, Huiwen1,2,3; Lv, Pengmei1,2,3,5; Yuan, Zhenhong1,2,3
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| 刊名 | JOURNAL OF BIOBASED MATERIALS AND BIOENERGY
 |
| 出版日期 | 2016-12-01 |
| 卷号 | 10期号:6页码:452-457 |
| 关键词 | Ionic Liquid Dimethyl Carbonate Glycerol Glycerol Carbonate |
| DOI | 10.1166/jbmb.2016.1625 |
| 文献子类 | Article |
| 英文摘要 | Acidic, basic and neutral ionic liquids (ILs) were prepared by two-step method. Their IR and NMR spectra showed that their structures were in accordance with their theoretical structure. Then these ILs were used as catalysts in the Glycerol carbonate (GC) of glycerol with dimethyl carbonate (DMC). The results show that basic ILs have high catalytic activity compared with acidic or neutral ILs and inorganic basic catalysts in the reaction. Under the suitable conditions using [Bmin]lm as a catalyst led to the yield of GC reached 94%, glycerol conversion reached 96%, GC selectivity reached 97% at molar ratio of DMC to glycerol at 3: 1, mass fraction of ionic liquid 12% (omega), reaction temperature 80 degrees C and reaction time 70 min. The ionic liquid was stable, and its activity did not decrease after using for 8 times (i. e., 85% glycerol conversion and near 90% GC selectivity). The results showed that the basic ionic liquid is more ideal green catalyst in esterification reaction. |
| 语种 | 英语 |
| WOS记录号 | WOS:000397803900009 |
| 资助机构 | State Key Program of National Nature Science Foundation of China(21506217) ; Natural Science Foundation of Guangdong Province(2016A030308004) |
| 源URL | [http://ir.giec.ac.cn/handle/344007/14094]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan Province, Peoples R China |
| 推荐引用方式 GB/T 7714 | Miao, Changlin,Fan, Pei,Zhuang, Xinshu,et al. Synthesis of Glycerol Carbonate from Glycerol and Dimethyl Carbonate Using Ionic Liquid Catalysts[J]. JOURNAL OF BIOBASED MATERIALS AND BIOENERGY,2016,10(6):452-457. |
| APA | Miao, Changlin.,Fan, Pei.,Zhuang, Xinshu.,Wang, Zhongming.,Li, Huiwen.,...&Yuan, Zhenhong.(2016).Synthesis of Glycerol Carbonate from Glycerol and Dimethyl Carbonate Using Ionic Liquid Catalysts.JOURNAL OF BIOBASED MATERIALS AND BIOENERGY,10(6),452-457. |
| MLA | Miao, Changlin,et al."Synthesis of Glycerol Carbonate from Glycerol and Dimethyl Carbonate Using Ionic Liquid Catalysts".JOURNAL OF BIOBASED MATERIALS AND BIOENERGY 10.6(2016):452-457. |
入库方式： OAI收割
来源：广州能源研究所
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