Sustainable biodiesel production via transesterification by using recyclable Ca2MgSi2O7 catalyst
文献类型：期刊论文
| 作者 | Wang, Jiayan1,2,3,4; Yang, Lingmei1,3,4 ; Luo, Wen1,3,4; Yang, Gaixiu1,3,4; Miao, Changlin1,3,4; Fu, Junying1,3,4; Xing, Shiyou1,3,4,6; Fan, Pei1,3,4,6; Lv, Pengmei1,3,4,5; Wang, Zhongming1,3,4
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| 刊名 | FUEL
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| 出版日期 | 2017-05-15 |
| 卷号 | 196页码:306-313 |
| 关键词 | Ca2mgsi2o7 (Akermanite) Solid Basic Catalyst Biodiesel Transesterification |
| DOI | 10.1016/j.fuel.2017.02.007 |
| 文献子类 | Article |
| 英文摘要 | Ca2MgSi2O7 has been investigated in the transesterification of rapeseed oil with a view to determining its viability as a solid base catalyst for use in biodiesel synthesis. This catalyst exhibited both high catalytic activity and reusability, giving a fatty acid methyl ester (FAME) conversion of 99% when the reaction was conducted with 20 wt% catalyst and a methanol/oil molar ratio of 10:1 at 190 degrees C over 6 h. The FAME conversion remained >85% after 16 cycles without catalyst compensation. BET test illustrates that Ca2MgSi2O7 has a narrow pore size distribution centred at 5.0 nm. Transesterification takes place on the catalyst surface, the basic characteristics or basicity of the catalyst decide greatly catalytic activity. CO2-TPD analysis showed that the total number of basic sites of akermanite is 0.8822 mmol.g(-1). This includes three different oxygen anions exhibiting different chemical environments on the catalyst surface. The basic strength of oxygen anions increased in the order 02 < 03 < 01, which were identified by XPS. In addition, the excellent reusability of the catalyst was associated with the presence of stable [MgO4] and [CaO8] structures. These results suggest that Ca2MgSi2O7 is a promising catalyst for biodiesel synthesis. (C) 2017 Elsevier Ltd. All rights reserved. |
| WOS关键词 | SOLID BASE CATALYST ; HETEROGENEOUS CATALYSTS ; CARBON-DIOXIDE ; SOYBEAN OIL ; AKERMANITE ; WASTE ; TRIGLYCERIDES ; TEMPERATURE ; OXIDE ; ACID |
| 语种 | 英语 |
| WOS记录号 | WOS:000397360200030 |
| 资助机构 | National Natural Science Foundation of China(21576260) ; Natural Science Foundation of Guangdong Province(2016A030308004 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 2015A030313720) |
| 源URL | [http://ir.giec.ac.cn/handle/344007/14106]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China 3.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 4.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China 5.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan Province, Peoples R China 6.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Jiayan,Yang, Lingmei,Luo, Wen,et al. Sustainable biodiesel production via transesterification by using recyclable Ca2MgSi2O7 catalyst[J]. FUEL,2017,196:306-313. |
| APA | Wang, Jiayan.,Yang, Lingmei.,Luo, Wen.,Yang, Gaixiu.,Miao, Changlin.,...&Wang, Zhongming.(2017).Sustainable biodiesel production via transesterification by using recyclable Ca2MgSi2O7 catalyst.FUEL,196,306-313. |
| MLA | Wang, Jiayan,et al."Sustainable biodiesel production via transesterification by using recyclable Ca2MgSi2O7 catalyst".FUEL 196(2017):306-313. |
入库方式： OAI收割
来源：广州能源研究所
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